TY - JOUR
T1 - Tetrakis(diphenylphosphino)allene
AU - Schmidbaur, Hubert
AU - Pollok, Thomas
PY - 1986/4
Y1 - 1986/4
N2 - A one‐pot reaction afforded the title compound 1, R Ph, in 60% yield via lithiation of 1‐diphenylphosphinopropyne with n BuLi followed by reaction with ClPPh2. The colorless, crystalline allene 1 is very reactive: for example, it reacts with oxygen, sulfur, and selenium to give the corresponding chalcogenides 2a‐c. (Figure Presented.)
AB - A one‐pot reaction afforded the title compound 1, R Ph, in 60% yield via lithiation of 1‐diphenylphosphinopropyne with n BuLi followed by reaction with ClPPh2. The colorless, crystalline allene 1 is very reactive: for example, it reacts with oxygen, sulfur, and selenium to give the corresponding chalcogenides 2a‐c. (Figure Presented.)
UR - https://www.scopus.com/pages/publications/84985534996
U2 - 10.1002/anie.198603481
DO - 10.1002/anie.198603481
M3 - Article
AN - SCOPUS:84985534996
SN - 0570-0833
VL - 25
SP - 348
EP - 349
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 4
ER -