@article{f41a80a78eef4352a2fecde4de141fe9,
title = "Term-values and valence-rydberg mixing in core-excited states, SiH4 and PH3",
abstract = "The controversial interpretation on the XUV spectra of PH3 and SiH4 have been examined experimentally and theoretically. An assigned consistent with measured 2p-absroption spectra of gaseous and solid SiH4 and PH3, and with CI calculation on core-excited states of SiH4 is presented. The predictions of the equivalent ionic core virtual orbital model are confirmed. Term-values for core-excited states differ systematically from those for valence-excited states.",
author = "H. Friedrich and B. Sonntag and P. Rabe and W. Butscher and Schwarz, {W. H.E.}",
note = "Funding Information: W-B_ thanks Professors Buenker and Peyerimhoff for the use of their CI and property programs. W_H.ES_ is grateful to Professor Peyerimhoff for the possibility of working at her insritute, for her hospitality and for discussions_ Our thanks are due to the Deutsche Forschungsgemeinschsft and the Fonds der Chemischen Industrie for finsncial support. The calculations have been performed at the RegionaIes Hochschulrechenzentrum Bonn_ The authors wish to dedicate this paper to Professor H. Hartmann on the occasion of his 65th birthday.",
year = "1979",
month = jul,
day = "1",
doi = "10.1016/0009-2614(79)80532-1",
language = "English",
volume = "64",
pages = "360--366",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "2",
}