Teaching an Old Dog New Tricks: Simple Selective and Regiodivergent Quinoline Hydrogenation

Florian Bourriquen, Julien Hervochon, Stephan Bartling, Nils Rockstroh, Cédric Fischmeister, Kathrin Junge, Matthias Beller

Research output: Contribution to journalArticlepeer-review

Abstract

A methodology for a regiodivergent hydrogenation of quinolines is reported using broadly available and commercial supported ruthenium catalysts. cis- or trans-Decahydroquinolines are obtained in high yield and high diastereoselectivity by simple variation of the catalyst and/or reaction temperature.

Original languageEnglish
Pages (from-to)12853-12858
Number of pages6
JournalACS Sustainable Chemistry and Engineering
Volume11
Issue number34
DOIs
StatePublished - 28 Aug 2023
Externally publishedYes

Keywords

  • arene hydrogenation
  • catalysis
  • heterocycles
  • regiodivergent hydrogenation

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