Tandem Suzuki-Miyaura/transfer hydrogenation reaction catalyzed by a Pd-Ru complex bearing an anionic dicarbene

Mario J. Bitzer; Fritz E. Kühn; Walter Baratta

doi:10.1016/j.jcat.2016.02.031

Tandem Suzuki-Miyaura/transfer hydrogenation reaction catalyzed by a Pd-Ru complex bearing an anionic dicarbene

Mario J. Bitzer, Fritz E. Kühn, Walter Baratta

Associate Professorship of Molecular Catalysis

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A hetero-bimetallic Pd-Ru N-Heterocyclic Dicarbene (NHDC) complex was synthesized from a Ag-Ru complex by transmetalation. The Pd-Ru system displays high catalytic activity in tandem Suzuki-Miyaura cross-coupling/transfer hydrogenation reaction of bromoaryl ketones with boronic acids in toluene and 2-propanol in the presence of KOH.

Original language	English
Pages (from-to)	222-226
Number of pages	5
Journal	Journal of Catalysis
Volume	338
DOIs	https://doi.org/10.1016/j.jcat.2016.02.031
State	Published - 1 Jun 2016

Keywords

Anionic dicarbenes
Bimetallic complexes
Cross-coupling
Tandem catalysis
Transfer hydrogenation

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10.1016/j.jcat.2016.02.031

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title = "Tandem Suzuki-Miyaura/transfer hydrogenation reaction catalyzed by a Pd-Ru complex bearing an anionic dicarbene",

abstract = "A hetero-bimetallic Pd-Ru N-Heterocyclic Dicarbene (NHDC) complex was synthesized from a Ag-Ru complex by transmetalation. The Pd-Ru system displays high catalytic activity in tandem Suzuki-Miyaura cross-coupling/transfer hydrogenation reaction of bromoaryl ketones with boronic acids in toluene and 2-propanol in the presence of KOH.",

keywords = "Anionic dicarbenes, Bimetallic complexes, Cross-coupling, Tandem catalysis, Transfer hydrogenation",

author = "Bitzer, {Mario J.} and K{\"u}hn, {Fritz E.} and Walter Baratta",

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doi = "10.1016/j.jcat.2016.02.031",

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T1 - Tandem Suzuki-Miyaura/transfer hydrogenation reaction catalyzed by a Pd-Ru complex bearing an anionic dicarbene

AU - Bitzer, Mario J.

AU - Kühn, Fritz E.

AU - Baratta, Walter

PY - 2016/6/1

Y1 - 2016/6/1

N2 - A hetero-bimetallic Pd-Ru N-Heterocyclic Dicarbene (NHDC) complex was synthesized from a Ag-Ru complex by transmetalation. The Pd-Ru system displays high catalytic activity in tandem Suzuki-Miyaura cross-coupling/transfer hydrogenation reaction of bromoaryl ketones with boronic acids in toluene and 2-propanol in the presence of KOH.

AB - A hetero-bimetallic Pd-Ru N-Heterocyclic Dicarbene (NHDC) complex was synthesized from a Ag-Ru complex by transmetalation. The Pd-Ru system displays high catalytic activity in tandem Suzuki-Miyaura cross-coupling/transfer hydrogenation reaction of bromoaryl ketones with boronic acids in toluene and 2-propanol in the presence of KOH.

KW - Anionic dicarbenes

KW - Bimetallic complexes

KW - Cross-coupling

KW - Tandem catalysis

KW - Transfer hydrogenation

UR - http://www.scopus.com/inward/record.url?scp=84962295470&partnerID=8YFLogxK

U2 - 10.1016/j.jcat.2016.02.031

DO - 10.1016/j.jcat.2016.02.031

M3 - Article

AN - SCOPUS:84962295470

SN - 0021-9517

VL - 338

SP - 222

EP - 226

JO - Journal of Catalysis

JF - Journal of Catalysis

ER -

Tandem Suzuki-Miyaura/transfer hydrogenation reaction catalyzed by a Pd-Ru complex bearing an anionic dicarbene

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Keywords

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