Abstract
The novel chlorogermyliumylidene complex L[ClGe:]+ (L = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a “naked” Cl- as a counter anion was synthesized through reaction of L with Cl2Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGeS]+ cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.
Original language | English |
---|---|
Pages (from-to) | 12198-12200 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 48 |
Issue number | 100 |
DOIs | |
State | Published - 21 Nov 2012 |
Externally published | Yes |