Synthesis, structure and complexes of a new bicyclic N,P-ligand derived from phosphatriazaadamantane

Bernd Assmann; Klaus Angermaier; Hubert Schmidbaur

doi:10.1039/C39940000941

Synthesis, structure and complexes of a new bicyclic N,P-ligand derived from phosphatriazaadamantane

Bernd Assmann, Klaus Angermaier, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Reductive cleavage of the methylphosphoniatriazaadamantane cation by sodium in liquid ammonia affords the new bicyclic ligand (MeP)(CH₂) ₅N₂(NMe) whose structure has been determined from crystals of its 1 : 1 complex with AuCl.

Original language	English
Pages (from-to)	941-942
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39940000941
State	Published - 1994

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title = "Synthesis, structure and complexes of a new bicyclic N,P-ligand derived from phosphatriazaadamantane",

abstract = "Reductive cleavage of the methylphosphoniatriazaadamantane cation by sodium in liquid ammonia affords the new bicyclic ligand (MeP)(CH2) 5N2(NMe) whose structure has been determined from crystals of its 1 : 1 complex with AuCl.",

author = "Bernd Assmann and Klaus Angermaier and Hubert Schmidbaur",

year = "1994",

doi = "10.1039/C39940000941",

language = "English",

pages = "941--942",

journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Synthesis, structure and complexes of a new bicyclic N,P-ligand derived from phosphatriazaadamantane

AU - Assmann, Bernd

AU - Angermaier, Klaus

AU - Schmidbaur, Hubert

PY - 1994

Y1 - 1994

N2 - Reductive cleavage of the methylphosphoniatriazaadamantane cation by sodium in liquid ammonia affords the new bicyclic ligand (MeP)(CH2) 5N2(NMe) whose structure has been determined from crystals of its 1 : 1 complex with AuCl.

AB - Reductive cleavage of the methylphosphoniatriazaadamantane cation by sodium in liquid ammonia affords the new bicyclic ligand (MeP)(CH2) 5N2(NMe) whose structure has been determined from crystals of its 1 : 1 complex with AuCl.

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U2 - 10.1039/C39940000941

DO - 10.1039/C39940000941

M3 - Article

AN - SCOPUS:37049069564

SN - 0022-4936

SP - 941

EP - 942

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Synthesis, structure and complexes of a new bicyclic N,P-ligand derived from phosphatriazaadamantane

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