Synthesis, structure and complexes of a new bicyclic N,P-ligand derived from phosphatriazaadamantane

Bernd Assmann, Klaus Angermaier, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

Reductive cleavage of the methylphosphoniatriazaadamantane cation by sodium in liquid ammonia affords the new bicyclic ligand (MeP)(CH2) 5N2(NMe) whose structure has been determined from crystals of its 1 : 1 complex with AuCl.

Original languageEnglish
Pages (from-to)941-942
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number8
DOIs
StatePublished - 1994
Externally publishedYes

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