Synthesis, Structure, and Bonding of the Cation [{(C6H5)3PAu}5C]⊕

Franz Scherbaum; Andreas Grohmann; Gerhard Müller; Hubert Schmidbaur

doi:10.1002/anie.198904631

Synthesis, Structure, and Bonding of the Cation [{(C₆H₅)₃PAu}₅C]^⊕

Franz Scherbaum
, Andreas Grohmann
, Gerhard Müller
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

199 Scopus citations

Abstract

An AuC bond order of 0.8 characterizes the pentaauriomethyl cation 1, so that the central carbon atom cannot be regarded as hypervalent. Compound 1 is formed from CH₂[B(OMe)₂]₂ and [Ph₃PAuCl] in the presence of CsF as BF 4⊖ salt in 84% yield. The trigonal‐bipyramidal coordination of the carbon center is slightly distorted. This may be due to a reduction in energy upon lowering the symmetry or to ligand–ligand repulsion or packing effects. (Figure Presented.)

Original language	English
Pages (from-to)	463-465
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	28
Issue number	4
DOIs	https://doi.org/10.1002/anie.198904631
State	Published - Apr 1989

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title = "Synthesis, Structure, and Bonding of the Cation [\{(C6H5)3PAu\}5C]⊕",

abstract = "An AuC bond order of 0.8 characterizes the pentaauriomethyl cation 1, so that the central carbon atom cannot be regarded as hypervalent. Compound 1 is formed from CH2[B(OMe)2]2 and [Ph3PAuCl] in the presence of CsF as BF 4⊖ salt in 84\% yield. The trigonal‐bipyramidal coordination of the carbon center is slightly distorted. This may be due to a reduction in energy upon lowering the symmetry or to ligand–ligand repulsion or packing effects. (Figure Presented.)",

author = "Franz Scherbaum and Andreas Grohmann and Gerhard M{\"u}ller and Hubert Schmidbaur",

year = "1989",

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doi = "10.1002/anie.198904631",

language = "English",

volume = "28",

pages = "463--465",

journal = "Angewandte Chemie International Edition in English",

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publisher = "John Wiley and Sons Ltd",

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T1 - Synthesis, Structure, and Bonding of the Cation [{(C6H5)3PAu}5C]⊕

AU - Scherbaum, Franz

AU - Grohmann, Andreas

AU - Müller, Gerhard

AU - Schmidbaur, Hubert

PY - 1989/4

Y1 - 1989/4

N2 - An AuC bond order of 0.8 characterizes the pentaauriomethyl cation 1, so that the central carbon atom cannot be regarded as hypervalent. Compound 1 is formed from CH2[B(OMe)2]2 and [Ph3PAuCl] in the presence of CsF as BF 4⊖ salt in 84% yield. The trigonal‐bipyramidal coordination of the carbon center is slightly distorted. This may be due to a reduction in energy upon lowering the symmetry or to ligand–ligand repulsion or packing effects. (Figure Presented.)

AB - An AuC bond order of 0.8 characterizes the pentaauriomethyl cation 1, so that the central carbon atom cannot be regarded as hypervalent. Compound 1 is formed from CH2[B(OMe)2]2 and [Ph3PAuCl] in the presence of CsF as BF 4⊖ salt in 84% yield. The trigonal‐bipyramidal coordination of the carbon center is slightly distorted. This may be due to a reduction in energy upon lowering the symmetry or to ligand–ligand repulsion or packing effects. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84990156916

U2 - 10.1002/anie.198904631

DO - 10.1002/anie.198904631

M3 - Article

AN - SCOPUS:84990156916

SN - 0570-0833

VL - 28

SP - 463

EP - 465

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 4

ER -

Synthesis, Structure, and Bonding of the Cation [{(C₆H₅)₃PAu}₅C]^⊕

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