Synthesis of the First Methylidyne‐Rhodium Cluster by Proton‐Induced H2/CH4‐Elimination from a μ‐Methylene Complex

Wolfgang A. Herrmann; Johann Plank; Ernst Guggolz; Manfred L. Ziegler

doi:10.1002/anie.198006511

Synthesis of the First Methylidyne‐Rhodium Cluster by Proton‐Induced H₂/CH₄‐Elimination from a μ‐Methylene Complex

Wolfgang A. Herrmann, Johann Plank, Ernst Guggolz, Manfred L. Ziegler

Research output: Contribution to journal › Article › peer-review

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Abstract

The transformation of a μ‐methylene‐dirhodium complex into a μ₃‐methylidyne‐trirhodium complex (X‐ray structure analysis) has been accomplished in reaction 1 → 3. The first step is protonation of 1 to form the (isolable) μ‐hydrido complex 2. (Formula Presented.)

Original language	English
Pages (from-to)	651-653
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	19
Issue number	8
DOIs	https://doi.org/10.1002/anie.198006511
State	Published - Aug 1980
Externally published	Yes

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10.1002/anie.198006511

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title = "Synthesis of the First Methylidyne‐Rhodium Cluster by Proton‐Induced H2/CH4‐Elimination from a μ‐Methylene Complex",

abstract = "The transformation of a μ‐methylene‐dirhodium complex into a μ3‐methylidyne‐trirhodium complex (X‐ray structure analysis) has been accomplished in reaction 1 → 3. The first step is protonation of 1 to form the (isolable) μ‐hydrido complex 2. (Formula Presented.)",

author = "Herrmann, {Wolfgang A.} and Johann Plank and Ernst Guggolz and Ziegler, {Manfred L.}",

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AU - Guggolz, Ernst

AU - Ziegler, Manfred L.

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AB - The transformation of a μ‐methylene‐dirhodium complex into a μ3‐methylidyne‐trirhodium complex (X‐ray structure analysis) has been accomplished in reaction 1 → 3. The first step is protonation of 1 to form the (isolable) μ‐hydrido complex 2. (Formula Presented.)

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Synthesis of the First Methylidyne‐Rhodium Cluster by Proton‐Induced H₂/CH₄‐Elimination from a μ‐Methylene Complex

Abstract

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