Synthesis of novel rhodium phosphite catalysts for efficient and selective isomerization-hydroformylation reactions

Irene Piras, Reiko Jennerjahn, Ralf Jackstell, Wolfgang Baumann, Anke Spannenberg, Robert Franke, Klaus Diether Wiese, Matthias Beller

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

New modular H8-BINOL-based phosphite ligands have been synthesized. High activity and regioselectivity has been achieved in the rhodium-catalyzed isomerization-hydroformylation of internal olefins. The active catalysts have been characterized by in situ NMR studies.

Original languageEnglish
Pages (from-to)479-486
Number of pages8
JournalJournal of Organometallic Chemistry
Volume695
Issue number4
DOIs
StatePublished - 15 Feb 2010
Externally publishedYes

Keywords

  • Bisphosphites
  • Homogeneous catalysis
  • Hydroformylation
  • Isomerization
  • Rhodium

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