Synthesis of functional methylphosphane-borane derivatives ii syntheses of chlorodimethylphosphane-borane, dime-thyl (amino)phosphane-borane and sodium (boranato-di-methylphosphinite): Precursors for the chemistry of the h3b(chf)2p-group

H. Schmidbaur; G. Muller

doi:10.1080/00945718508061409

Synthesis of functional methylphosphane-borane derivatives ii syntheses of chlorodimethylphosphane-borane, dime-thyl (amino)phosphane-borane and sodium (boranato-di-methylphosphinite): Precursors for the chemistry of the h₃b(ch_f)₂p-group

H. Schmidbaur, G. Muller

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A convenient large-scale synthesis of chloro-dimethylphosphane-borane from the phosphane and bo-rane-tetrahydrofuran adduct is described. The product is the starting material for the chemistry with the H₃b(chj)₂P-group as illustrated by the examples dimethyl(amino)phosphane-borane and sodium (boranato-dimethylphosphinite).

Original language	English
Pages (from-to)	415-423
Number of pages	9
Journal	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume	15
Issue number	4
DOIs	https://doi.org/10.1080/00945718508061409
State	Published - 1 Jan 1985
Externally published	Yes

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Schmidbaur, H., & Muller, G. (1985). Synthesis of functional methylphosphane-borane derivatives ii syntheses of chlorodimethylphosphane-borane, dime-thyl (amino)phosphane-borane and sodium (boranato-di-methylphosphinite): Precursors for the chemistry of the h₃b(ch_f)₂p-group. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 15(4), 415-423. https://doi.org/10.1080/00945718508061409

Schmidbaur, H. ; Muller, G. / Synthesis of functional methylphosphane-borane derivatives ii syntheses of chlorodimethylphosphane-borane, dime-thyl (amino)phosphane-borane and sodium (boranato-di-methylphosphinite) : Precursors for the chemistry of the h₃b(ch_f)₂p-group. In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 1985 ; Vol. 15, No. 4. pp. 415-423.

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abstract = "A convenient large-scale synthesis of chloro-dimethylphosphane-borane from the phosphane and bo-rane-tetrahydrofuran adduct is described. The product is the starting material for the chemistry with the H3b(chj)2P-group as illustrated by the examples dimethyl(amino)phosphane-borane and sodium (boranato-dimethylphosphinite).",

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Schmidbaur, H & Muller, G 1985, 'Synthesis of functional methylphosphane-borane derivatives ii syntheses of chlorodimethylphosphane-borane, dime-thyl (amino)phosphane-borane and sodium (boranato-di-methylphosphinite): Precursors for the chemistry of the h₃b(ch_f)₂p-group', Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 15, no. 4, pp. 415-423. https://doi.org/10.1080/00945718508061409

Synthesis of functional methylphosphane-borane derivatives ii syntheses of chlorodimethylphosphane-borane, dime-thyl (amino)phosphane-borane and sodium (boranato-di-methylphosphinite): Precursors for the chemistry of the h₃b(ch_f)₂p-group. / Schmidbaur, H.; Muller, G.
In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Vol. 15, No. 4, 01.01.1985, p. 415-423.

Research output: Contribution to journal › Article › peer-review

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Schmidbaur H, Muller G. Synthesis of functional methylphosphane-borane derivatives ii syntheses of chlorodimethylphosphane-borane, dime-thyl (amino)phosphane-borane and sodium (boranato-di-methylphosphinite): Precursors for the chemistry of the h₃b(ch_f)₂p-group. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 1985 Jan 1;15(4):415-423. doi: 10.1080/00945718508061409