Synthesis of Carbocyclic Carbene Complexes by Metal‐Induced Diazocyclopentadiene Fragmentation

Wolfgang A. Herrmann; Johann Plank; Manfred L. Ziegler; Klaus Weidenhammer

doi:10.1002/anie.197807771

Synthesis of Carbocyclic Carbene Complexes by Metal‐Induced Diazocyclopentadiene Fragmentation

Wolfgang A. Herrmann, Johann Plank, Manfred L. Ziegler, Klaus Weidenhammer

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22 Scopus citations

Abstract

The first metal complex to contain an oligocyclic dicarbene is formed as a result of a hitherto unobserved [2+2] cycloaddition of the carbene liberated from 1. The structure of 2 is confirmed by X‐ray structure analysis. (Figure Presented.)

Original language	English
Pages (from-to)	777-778
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	17
Issue number	10
DOIs	https://doi.org/10.1002/anie.197807771
State	Published - Oct 1978
Externally published	Yes

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title = "Synthesis of Carbocyclic Carbene Complexes by Metal‐Induced Diazocyclopentadiene Fragmentation",

abstract = "The first metal complex to contain an oligocyclic dicarbene is formed as a result of a hitherto unobserved [2+2] cycloaddition of the carbene liberated from 1. The structure of 2 is confirmed by X‐ray structure analysis. (Figure Presented.)",

author = "Herrmann, {Wolfgang A.} and Johann Plank and Ziegler, {Manfred L.} and Klaus Weidenhammer",

year = "1978",

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AU - Herrmann, Wolfgang A.

AU - Plank, Johann

AU - Ziegler, Manfred L.

AU - Weidenhammer, Klaus

PY - 1978/10

Y1 - 1978/10

N2 - The first metal complex to contain an oligocyclic dicarbene is formed as a result of a hitherto unobserved [2+2] cycloaddition of the carbene liberated from 1. The structure of 2 is confirmed by X‐ray structure analysis. (Figure Presented.)

AB - The first metal complex to contain an oligocyclic dicarbene is formed as a result of a hitherto unobserved [2+2] cycloaddition of the carbene liberated from 1. The structure of 2 is confirmed by X‐ray structure analysis. (Figure Presented.)

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DO - 10.1002/anie.197807771

M3 - Article

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IS - 10

ER -

Synthesis of Carbocyclic Carbene Complexes by Metal‐Induced Diazocyclopentadiene Fragmentation

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