Synthesis and X-ray structure of [(THF)K(C5H4CH2CH2PPh2)]∞: A structurally characterized heavier alkali metal phosphane complex

Hans H. Karsch; Volker W. Graf; Manfred Reisky

doi:10.1039/a904248b

Synthesis and X-ray structure of [(THF)K(C₅H₄CH₂CH₂PPh₂)]∞: A structurally characterized heavier alkali metal phosphane complex

Hans H. Karsch
, Volker W. Graf
, Manfred Reisky

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Reaction of spiro[2.4]hepta-4,6-diene with KPPh₂ in THF gives K(C₅H₄CH₂CH₂PPh₂) 1, which crystallizes from THF and shows coordination of a neutral phosphane functionality to potassium.

Original language	English
Pages (from-to)	1695-1696
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/a904248b
State	Published - 7 Sep 1999

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@article{3834835f36cc4d329b25654b62806acd,

title = "Synthesis and X-ray structure of [(THF)K(C5H4CH2CH2PPh2)]∞: A structurally characterized heavier alkali metal phosphane complex",

abstract = "Reaction of spiro[2.4]hepta-4,6-diene with KPPh2 in THF gives K(C5H4CH2CH2PPh2) 1, which crystallizes from THF and shows coordination of a neutral phosphane functionality to potassium.",

author = "Karsch, \{Hans H.\} and Graf, \{Volker W.\} and Manfred Reisky",

year = "1999",

month = sep,

day = "7",

doi = "10.1039/a904248b",

language = "English",

pages = "1695--1696",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - Synthesis and X-ray structure of [(THF)K(C5H4CH2CH2PPh2)]∞

T2 - A structurally characterized heavier alkali metal phosphane complex

AU - Karsch, Hans H.

AU - Graf, Volker W.

AU - Reisky, Manfred

PY - 1999/9/7

Y1 - 1999/9/7

N2 - Reaction of spiro[2.4]hepta-4,6-diene with KPPh2 in THF gives K(C5H4CH2CH2PPh2) 1, which crystallizes from THF and shows coordination of a neutral phosphane functionality to potassium.

AB - Reaction of spiro[2.4]hepta-4,6-diene with KPPh2 in THF gives K(C5H4CH2CH2PPh2) 1, which crystallizes from THF and shows coordination of a neutral phosphane functionality to potassium.

UR - https://www.scopus.com/pages/publications/0033533482

U2 - 10.1039/a904248b

DO - 10.1039/a904248b

M3 - Article

AN - SCOPUS:0033533482

SN - 1359-7345

SP - 1695

EP - 1696

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Synthesis and X-ray structure of [(THF)K(C₅H₄CH₂CH₂PPh₂)]∞: A structurally characterized heavier alkali metal phosphane complex

Abstract

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