Synthesis and structure of trans-dichloro-tetra(pyrazole)-gallium(III) chloride and tetrachlorogallate(III)

Stefan Nogai; Annette Schier; Hubert Schmidbaur

doi:10.1515/znb-2002-0209

Synthesis and structure of trans-dichloro-tetra(pyrazole)-gallium(III) chloride and tetrachlorogallate(III)

Stefan Nogai
, Annette Schier
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

[GaCl₂(pyrazole)₄]⁺Cl^- and [GaCl₂(pyrazole)₄]⁺GaCl₄ ^- are formed in the reaction of pyrazole and anhydrous gallium trichloride in toluene/diethyl ether. The crystal structure of the chloride salt shows cations in a trans-conufiguration which are associated with the chloride counterions through N-H- -Cl hydrogen bonds.

Original language	English
Pages (from-to)	183-186
Number of pages	4
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	57
Issue number	2
DOIs	https://doi.org/10.1515/znb-2002-0209
State	Published - 2002

Keywords

Bioinorganic Chemistry
Gallium Complexes
Pyrazole Complexes

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title = "Synthesis and structure of trans-dichloro-tetra(pyrazole)-gallium(III) chloride and tetrachlorogallate(III)",

abstract = "[GaCl2(pyrazole)4]+Cl- and [GaCl2(pyrazole)4]+GaCl4 - are formed in the reaction of pyrazole and anhydrous gallium trichloride in toluene/diethyl ether. The crystal structure of the chloride salt shows cations in a trans-conufiguration which are associated with the chloride counterions through N-H- -Cl hydrogen bonds.",

keywords = "Bioinorganic Chemistry, Gallium Complexes, Pyrazole Complexes",

author = "Stefan Nogai and Annette Schier and Hubert Schmidbaur",

year = "2002",

doi = "10.1515/znb-2002-0209",

language = "English",

volume = "57",

pages = "183--186",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

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T1 - Synthesis and structure of trans-dichloro-tetra(pyrazole)-gallium(III) chloride and tetrachlorogallate(III)

AU - Nogai, Stefan

AU - Schier, Annette

AU - Schmidbaur, Hubert

PY - 2002

Y1 - 2002

N2 - [GaCl2(pyrazole)4]+Cl- and [GaCl2(pyrazole)4]+GaCl4 - are formed in the reaction of pyrazole and anhydrous gallium trichloride in toluene/diethyl ether. The crystal structure of the chloride salt shows cations in a trans-conufiguration which are associated with the chloride counterions through N-H- -Cl hydrogen bonds.

AB - [GaCl2(pyrazole)4]+Cl- and [GaCl2(pyrazole)4]+GaCl4 - are formed in the reaction of pyrazole and anhydrous gallium trichloride in toluene/diethyl ether. The crystal structure of the chloride salt shows cations in a trans-conufiguration which are associated with the chloride counterions through N-H- -Cl hydrogen bonds.

KW - Bioinorganic Chemistry

KW - Gallium Complexes

KW - Pyrazole Complexes

UR - https://www.scopus.com/pages/publications/0036333745

U2 - 10.1515/znb-2002-0209

DO - 10.1515/znb-2002-0209

M3 - Article

AN - SCOPUS:0036333745

SN - 0932-0776

VL - 57

SP - 183

EP - 186

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 2

ER -

Synthesis and structure of trans-dichloro-tetra(pyrazole)-gallium(III) chloride and tetrachlorogallate(III)

Abstract

Keywords

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