Synthesis and structure of benzyltriethylammonium trichlorogermanate(II)

Gerald L. Wegner, Alexander Jockisch, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The reaction of equimolar quantities of GeCl2 · dioxane with [BzEt3N]+ Cl- in tetrahydronaphthaline gives high yields of [BzEt3N]+ [GeCl3]-. The asymmetric unit of the monoclinic single crystals (from CH2Cl2, space group P21/c, Z = 8) are comprising two pairs of crystallographically independent cations and anions, each with very similar molecular dimensions. The isolated [GeCl3]- anions have a trigonal pyramidal structure with narrow Cl-Ge-Cl angles in the range from 93.41(5) to 98.27(5)° and Ge-Cl distances between 2.293(2) and 2.305(2) Å. This structure is thus very similar to that of the isoelectronic AsCl3 molecule and of the [SeCl3]+ cation.

Original languageEnglish
Pages (from-to)430-433
Number of pages4
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume53
Issue number4
DOIs
StatePublished - Apr 1998
Externally publishedYes

Keywords

  • Germanium Dichloride
  • Trichlorogermanate(II)

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