Synthesis and structure of an ionic beryllium-"carbene" complex

Wolfgang A. Herrmann; Oliver Runte; Georg Artus

doi:10.1016/0022-328X(95)05615-V

Synthesis and structure of an ionic beryllium-"carbene" complex

Wolfgang A. Herrmann, Oliver Runte, Georg Artus

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

156 Scopus citations

Abstract

The Lewis-acidic metal ion Be²⁺ forms stable adducts with the carbene 1,3-dimethylimidazolin-2-ylidene (L). The pronounced nucleophilicity of the ligand is encountered in the cleavage of the polymeric structure of BeCl₂ with consecutive heterolysis to yield the ionic coordination compound [L₃BeCl]⁺Cl^-.

Original language	English
Pages (from-to)	C1-C4
Journal	Journal of Organometallic Chemistry
Volume	501
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(95)05615-V
State	Published - 4 Oct 1995

Keywords

Beryllium
Crystal structure
Heterocyclic carbene

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10.1016/0022-328X(95)05615-V

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title = "Synthesis and structure of an ionic beryllium-{"}carbene{"} complex",

abstract = "The Lewis-acidic metal ion Be2+ forms stable adducts with the carbene 1,3-dimethylimidazolin-2-ylidene (L). The pronounced nucleophilicity of the ligand is encountered in the cleavage of the polymeric structure of BeCl2 with consecutive heterolysis to yield the ionic coordination compound [L3BeCl]+Cl-.",

keywords = "Beryllium, Crystal structure, Heterocyclic carbene",

author = "Herrmann, \{Wolfgang A.\} and Oliver Runte and Georg Artus",

year = "1995",

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doi = "10.1016/0022-328X(95)05615-V",

language = "English",

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T1 - Synthesis and structure of an ionic beryllium-"carbene" complex

AU - Herrmann, Wolfgang A.

AU - Runte, Oliver

AU - Artus, Georg

PY - 1995/10/4

Y1 - 1995/10/4

N2 - The Lewis-acidic metal ion Be2+ forms stable adducts with the carbene 1,3-dimethylimidazolin-2-ylidene (L). The pronounced nucleophilicity of the ligand is encountered in the cleavage of the polymeric structure of BeCl2 with consecutive heterolysis to yield the ionic coordination compound [L3BeCl]+Cl-.

AB - The Lewis-acidic metal ion Be2+ forms stable adducts with the carbene 1,3-dimethylimidazolin-2-ylidene (L). The pronounced nucleophilicity of the ligand is encountered in the cleavage of the polymeric structure of BeCl2 with consecutive heterolysis to yield the ionic coordination compound [L3BeCl]+Cl-.

KW - Beryllium

KW - Crystal structure

KW - Heterocyclic carbene

UR - http://www.scopus.com/inward/record.url?scp=14544306544&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(95)05615-V

DO - 10.1016/0022-328X(95)05615-V

M3 - Article

AN - SCOPUS:14544306544

SN - 0022-328X

VL - 501

SP - C1-C4

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Synthesis and structure of an ionic beryllium-"carbene" complex

Abstract

Keywords

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