Synthesis and Structural Characterization of [cis-(Cy2PCH2CH2PCy2)(neo-Pe)PtGa(neo-Pe)2] (Cy = c-C6H11; neo-Pe = CH2C(CH3)3)

R. A. Fischer; H. D. Kaesz; S. I. Khan; H. J. Müller

doi:10.1021/ic00334a004

Synthesis and Structural Characterization of [cis-(Cy₂PCH₂CH₂PCy₂)(neo-Pe)PtGa(neo-Pe)₂] (Cy = c-C₆H₁₁; neo-Pe = CH₂C(CH₃)₃)

R. A. Fischer, H. D. Kaesz, S. I. Khan, H. J. Müller

University of California at Los Angeles

Research output: Contribution to journal › Article › peer-review

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Abstract

We have been interested in the synthesis of organotransitionmetal-group III¹complexes to serve as precursors for the deposition of intermetallic films²of specified composition using organometallic chemical vapor deposition (OMCVD).³Mixed-metal complexes such as dichloro(tetracarbonylcobalt)gallium(III) tetrahydrofuranate⁴or platinumbis(dimethylglyoximato)bis(di-methylgallium)⁵have given depositions of CoGa or PtGa₂⁶that are crystalline and highly reflective. However, these contain trace contaminations of heteroatoms derived from the ligands. On the way to synthesize other mixed metal complexes we examined the interaction of organogallium compounds with platinum derivatives that were known to give rise to reactive, coordinatively unsaturated fragments.^7,8.

Original language	English
Pages (from-to)	1601-1602
Number of pages	2
Journal	Inorganic Chemistry
Volume	29
Issue number	9
DOIs	https://doi.org/10.1021/ic00334a004
State	Published - May 1990
Externally published	Yes

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title = "Synthesis and Structural Characterization of [cis-(Cy2PCH2CH2PCy2)(neo-Pe)PtGa(neo-Pe)2] (Cy = c-C6H11; neo-Pe = CH2C(CH3)3)",

abstract = "We have been interested in the synthesis of organotransitionmetal-group III1complexes to serve as precursors for the deposition of intermetallic films2of specified composition using organometallic chemical vapor deposition (OMCVD).3Mixed-metal complexes such as dichloro(tetracarbonylcobalt)gallium(III) tetrahydrofuranate4or platinumbis(dimethylglyoximato)bis(di-methylgallium)5have given depositions of CoGa or PtGa26that are crystalline and highly reflective. However, these contain trace contaminations of heteroatoms derived from the ligands. On the way to synthesize other mixed metal complexes we examined the interaction of organogallium compounds with platinum derivatives that were known to give rise to reactive, coordinatively unsaturated fragments.7,8.",

author = "Fischer, {R. A.} and Kaesz, {H. D.} and Khan, {S. I.} and M{\"u}ller, {H. J.}",

year = "1990",

month = may,

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volume = "29",

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journal = "Inorganic Chemistry",

issn = "0020-1669",

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T1 - Synthesis and Structural Characterization of [cis-(Cy2PCH2CH2PCy2)(neo-Pe)PtGa(neo-Pe)2] (Cy = c-C6H11; neo-Pe = CH2C(CH3)3)

AU - Fischer, R. A.

AU - Kaesz, H. D.

AU - Khan, S. I.

AU - Müller, H. J.

PY - 1990/5

Y1 - 1990/5

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AB - We have been interested in the synthesis of organotransitionmetal-group III1complexes to serve as precursors for the deposition of intermetallic films2of specified composition using organometallic chemical vapor deposition (OMCVD).3Mixed-metal complexes such as dichloro(tetracarbonylcobalt)gallium(III) tetrahydrofuranate4or platinumbis(dimethylglyoximato)bis(di-methylgallium)5have given depositions of CoGa or PtGa26that are crystalline and highly reflective. However, these contain trace contaminations of heteroatoms derived from the ligands. On the way to synthesize other mixed metal complexes we examined the interaction of organogallium compounds with platinum derivatives that were known to give rise to reactive, coordinatively unsaturated fragments.7,8.

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Synthesis and Structural Characterization of [cis-(Cy₂PCH₂CH₂PCy₂)(neo-Pe)PtGa(neo-Pe)₂] (Cy = c-C₆H₁₁; neo-Pe = CH₂C(CH₃)₃)

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