Synthesis and properties of (TriptyTHACcenedicarboxylatio)zinc coordination networks

Sergei I. Vagin; Anna K. Ott; Stephan D. Hoffmann; Dominic Lanzinger; Bernhard Rieger

doi:10.1002/chem.200802691

Synthesis and properties of (TriptyTHACcenedicarboxylatio)zinc coordination networks

Sergei I. Vagin, Anna K. Ott, Stephan D. Hoffmann, Dominic Lanzinger, Bernhard Rieger

Wacker-Chair of Macromolecular Chemistry

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

(Triptycenedicarboxylato)-zinc metal-organic frameworks (MOFs) based on paddle wheel secondary building units (SBUs) with different axial ligands have been prepared. The reproducible formation of the layered paddle-wheel structures from trip-tycenedicarboxylic acid (H₂TDC) and zinc nitrate under various conditions seems to be characteristic of this acid and is utilized for the construction of 3D frameworks by a pillaring approach. We attempted to bring additional functionalities into MOFs by em- ploying the appropriate pillaring ligands, for example, bis(4-pyridyl)-s-tet-razine and bis(4-pyridyl)-dimethoxy- p-phenylenedivinylene, and investigated certain properties of some MOF materials, such as guest-exchange behavior, luminescence, microporosity, and stability.

Original language	English
Pages (from-to)	5845-5853
Number of pages	9
Journal	Chemistry - A European Journal
Volume	15
Issue number	23
DOIs	https://doi.org/10.1002/chem.200802691
State	Published - 2 Jun 2009

Keywords

Layered compounds metal-organic frameworks
Micro-porous materials
Solid-state structures
Zinc

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10.1002/chem.200802691

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abstract = "(Triptycenedicarboxylato)-zinc metal-organic frameworks (MOFs) based on paddle wheel secondary building units (SBUs) with different axial ligands have been prepared. The reproducible formation of the layered paddle-wheel structures from trip-tycenedicarboxylic acid (H2TDC) and zinc nitrate under various conditions seems to be characteristic of this acid and is utilized for the construction of 3D frameworks by a pillaring approach. We attempted to bring additional functionalities into MOFs by em- ploying the appropriate pillaring ligands, for example, bis(4-pyridyl)-s-tet-razine and bis(4-pyridyl)-dimethoxy- p-phenylenedivinylene, and investigated certain properties of some MOF materials, such as guest-exchange behavior, luminescence, microporosity, and stability.",

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T1 - Synthesis and properties of (TriptyTHACcenedicarboxylatio)zinc coordination networks

AU - Vagin, Sergei I.

AU - Ott, Anna K.

AU - Hoffmann, Stephan D.

AU - Lanzinger, Dominic

AU - Rieger, Bernhard

PY - 2009/6/2

Y1 - 2009/6/2

N2 - (Triptycenedicarboxylato)-zinc metal-organic frameworks (MOFs) based on paddle wheel secondary building units (SBUs) with different axial ligands have been prepared. The reproducible formation of the layered paddle-wheel structures from trip-tycenedicarboxylic acid (H2TDC) and zinc nitrate under various conditions seems to be characteristic of this acid and is utilized for the construction of 3D frameworks by a pillaring approach. We attempted to bring additional functionalities into MOFs by em- ploying the appropriate pillaring ligands, for example, bis(4-pyridyl)-s-tet-razine and bis(4-pyridyl)-dimethoxy- p-phenylenedivinylene, and investigated certain properties of some MOF materials, such as guest-exchange behavior, luminescence, microporosity, and stability.

AB - (Triptycenedicarboxylato)-zinc metal-organic frameworks (MOFs) based on paddle wheel secondary building units (SBUs) with different axial ligands have been prepared. The reproducible formation of the layered paddle-wheel structures from trip-tycenedicarboxylic acid (H2TDC) and zinc nitrate under various conditions seems to be characteristic of this acid and is utilized for the construction of 3D frameworks by a pillaring approach. We attempted to bring additional functionalities into MOFs by em- ploying the appropriate pillaring ligands, for example, bis(4-pyridyl)-s-tet-razine and bis(4-pyridyl)-dimethoxy- p-phenylenedivinylene, and investigated certain properties of some MOF materials, such as guest-exchange behavior, luminescence, microporosity, and stability.

KW - Layered compounds metal-organic frameworks

KW - Micro-porous materials

KW - Solid-state structures

KW - Zinc

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Synthesis and properties of (TriptyTHACcenedicarboxylatio)zinc coordination networks

Abstract

Keywords

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