Synthesis and isolation of a cyclic bis-vinyl germylene via a diazoolefin adduct of germylene dichloride

Teresa Eisner; Arseni Kostenko; Fiona J. Kiefer; Shigeyoshi Inoue

doi:10.1039/d3cc05090d

Synthesis and isolation of a cyclic bis-vinyl germylene via a diazoolefin adduct of germylene dichloride

Teresa Eisner, Arseni Kostenko, Fiona J. Kiefer, Shigeyoshi Inoue

Associate Professorship of Silicon Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Since the successful isolation of various stable diazoolefins, an array of complexes containing these promising ligands have been synthesized. We herein report the synthesis, characterization, and structures of neutral group 14 diazoolefin complexes and the subsequent transformation into a new cyclic bis-vinyl germylene.

Original language	English
Pages (from-to)	558-561
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	5
DOIs	https://doi.org/10.1039/d3cc05090d
State	Published - 7 Dec 2023

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title = "Synthesis and isolation of a cyclic bis-vinyl germylene via a diazoolefin adduct of germylene dichloride",

abstract = "Since the successful isolation of various stable diazoolefins, an array of complexes containing these promising ligands have been synthesized. We herein report the synthesis, characterization, and structures of neutral group 14 diazoolefin complexes and the subsequent transformation into a new cyclic bis-vinyl germylene.",

author = "Teresa Eisner and Arseni Kostenko and {J. Kiefer}, Fiona and Shigeyoshi Inoue",

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T1 - Synthesis and isolation of a cyclic bis-vinyl germylene via a diazoolefin adduct of germylene dichloride

AU - Eisner, Teresa

AU - Kostenko, Arseni

AU - J. Kiefer, Fiona

AU - Inoue, Shigeyoshi

PY - 2023/12/7

Y1 - 2023/12/7

N2 - Since the successful isolation of various stable diazoolefins, an array of complexes containing these promising ligands have been synthesized. We herein report the synthesis, characterization, and structures of neutral group 14 diazoolefin complexes and the subsequent transformation into a new cyclic bis-vinyl germylene.

AB - Since the successful isolation of various stable diazoolefins, an array of complexes containing these promising ligands have been synthesized. We herein report the synthesis, characterization, and structures of neutral group 14 diazoolefin complexes and the subsequent transformation into a new cyclic bis-vinyl germylene.

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U2 - 10.1039/d3cc05090d

DO - 10.1039/d3cc05090d

M3 - Article

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AN - SCOPUS:85180089129

SN - 1359-7345

VL - 60

SP - 558

EP - 561

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Synthesis and isolation of a cyclic bis-vinyl germylene via a diazoolefin adduct of germylene dichloride

Abstract

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