Synthesis and Crystal Stucture of a Salt Containing the Anion ; Precursors and Related Compounds

Hubert Schmidbaur, Erwin Weiss, Beate Zimmer‐Gasser

Research output: Contribution to journalArticlepeer-review

53 Scopus citations

Abstract

Metalation of the central C atom of the bis(phosphane‐borane) 1 is feasible with alkyllithium; the complex salt 2 can be precipitated with TMEDA. According to X‐ray structure analysis, the distances in the non‐linear PCP bridge are almost equal and shorter than the terminal PC bonds, thus establishing the ylidic nature of the bridge. (Figure Presented.)

Original languageEnglish
Pages (from-to)782-784
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume18
Issue number10
DOIs
StatePublished - Oct 1979
Externally publishedYes

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