Synthesis and crystal structure of [K([2.2]crypt)] 2[HgGe 9](dmf) 1

M. Bele Boeddinghaus, Stephan D. Hoffmann, Thomas F. Fässler

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Abstract

The title compound [K([2.2]crypt)] 2[HgGe 9](dmf) 1) (1) has been obtained by reaction of elemental mercury with the binary phase of the formal composition K 4Ge 9 in dmf and after addition of [2.2]crypt. The X-ray single crystal analysis shows that 1 contains polymeric 1[HgGe 9] 2- units in which Ge 9 clusters are linked together by mercury atoms. The differences in the structures of 1 and the related compound [K([2.2.2]crypt)] 2[HgGe 9](en) 2 2) 2 are discussed.

Original languageEnglish
Pages (from-to)2338-2341
Number of pages4
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume633
Issue number13-14
DOIs
StatePublished - 2007

Keywords

  • Cluster compounds
  • Crystal structure
  • Germanium
  • Mercury
  • Zintl ion

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