Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41

Sandra Gago; Yanmei Zhang; Ana M. Santos; Klaus Köhler; Fritz E. Kühn; José A. Fernandes; Martyn Pillinger; Anabela A. Valente; Teresa M. Santos; Paulo J.A. Ribeiro-Claro; Isabel S. Gonçalves

doi:10.1016/j.micromeso.2004.08.006

Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41

Sandra Gago
, Yanmei Zhang
, Ana M. Santos
, Klaus Köhler
, Fritz E. Kühn
, José A. Fernandes
, Martyn Pillinger
, Anabela A. Valente
, Teresa M. Santos
, Paulo J.A. Ribeiro-Claro
, Isabel S. Gonçalves

University of Aveiro
Technical University of Munich

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

The acetonitrile complex [Mn(NCCH₃₎₆] [B(C₆F _5)4]2 has been immobilized in the ordered mesoporous silica MCM-41 functionalized with a pyrazolylpyridine (PP) ligand. A metal loading of 0.72 wt.% (0.13mmolg^-1) was achieved. Powder X-ray diffraction and N ₂ adsorption-desorption analysis of the derivatized material confirmed that the textural properties of the hexagonally ordered host were preserved during the grafting experiment and that the channels remained accessible, despite reductions in surface area and pore volume. The derivatized material was also characterized by thermogravimetric analysis and vibrational spectroscopy.

Original language	English
Pages (from-to)	131-136
Number of pages	6
Journal	Microporous and Mesoporous Materials
Volume	76
Issue number	1-3
DOIs	https://doi.org/10.1016/j.micromeso.2004.08.006
State	Published - 1 Dec 2004

Keywords

Acetonitrile complexes
Cationic polymerization
Chelating ligands
Immobilization
Manganese
Mesoporous materials

Access to Document

10.1016/j.micromeso.2004.08.006

Cite this

Gago, S., Zhang, Y., Santos, A. M., Köhler, K., Kühn, F. E., Fernandes, J. A., Pillinger, M., Valente, A. A., Santos, T. M., Ribeiro-Claro, P. J. A., & Gonçalves, I. S. (2004). Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41. Microporous and Mesoporous Materials, 76(1-3), 131-136. https://doi.org/10.1016/j.micromeso.2004.08.006

@article{419523f1a6e649109733704aa5f43fa9,

title = "Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41",

abstract = "The acetonitrile complex [Mn(NCCH3)6] [B(C6F 5)4]2 has been immobilized in the ordered mesoporous silica MCM-41 functionalized with a pyrazolylpyridine (PP) ligand. A metal loading of 0.72 wt.\% (0.13mmolg-1) was achieved. Powder X-ray diffraction and N 2 adsorption-desorption analysis of the derivatized material confirmed that the textural properties of the hexagonally ordered host were preserved during the grafting experiment and that the channels remained accessible, despite reductions in surface area and pore volume. The derivatized material was also characterized by thermogravimetric analysis and vibrational spectroscopy.",

keywords = "Acetonitrile complexes, Cationic polymerization, Chelating ligands, Immobilization, Manganese, Mesoporous materials",

author = "Sandra Gago and Yanmei Zhang and Santos, \{Ana M.\} and Klaus K{\"o}hler and K{\"u}hn, \{Fritz E.\} and Fernandes, \{Jos{\'e} A.\} and Martyn Pillinger and Valente, \{Anabela A.\} and Santos, \{Teresa M.\} and Ribeiro-Claro, \{Paulo J.A.\} and Gon{\c c}alves, \{Isabel S.\}",

note = "Funding Information: We are grateful to the FCT (Portugal), CRUP/DAAD (Ac{\c c}{\~o}es Integradas Programme), Alexander von Humboldt foundation (A.M.S.), the Fonds der Chemischen Industrie, the German Research Foundation, DFG, and the University of Aveiro (S.G.) for financial support and research grants.",

year = "2004",

month = dec,

day = "1",

doi = "10.1016/j.micromeso.2004.08.006",

language = "English",

volume = "76",

pages = "131--136",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

number = "1-3",

}

Gago, S, Zhang, Y, Santos, AM, Köhler, K , Kühn, FE, Fernandes, JA, Pillinger, M, Valente, AA, Santos, TM, Ribeiro-Claro, PJA & Gonçalves, IS 2004, 'Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41', Microporous and Mesoporous Materials, vol. 76, no. 1-3, pp. 131-136. https://doi.org/10.1016/j.micromeso.2004.08.006

TY - JOUR

T1 - Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41

AU - Gago, Sandra

AU - Zhang, Yanmei

AU - Santos, Ana M.

AU - Köhler, Klaus

AU - Kühn, Fritz E.

AU - Fernandes, José A.

AU - Pillinger, Martyn

AU - Valente, Anabela A.

AU - Santos, Teresa M.

AU - Ribeiro-Claro, Paulo J.A.

AU - Gonçalves, Isabel S.

N1 - Funding Information: We are grateful to the FCT (Portugal), CRUP/DAAD (Acções Integradas Programme), Alexander von Humboldt foundation (A.M.S.), the Fonds der Chemischen Industrie, the German Research Foundation, DFG, and the University of Aveiro (S.G.) for financial support and research grants.

PY - 2004/12/1

Y1 - 2004/12/1

N2 - The acetonitrile complex [Mn(NCCH3)6] [B(C6F 5)4]2 has been immobilized in the ordered mesoporous silica MCM-41 functionalized with a pyrazolylpyridine (PP) ligand. A metal loading of 0.72 wt.% (0.13mmolg-1) was achieved. Powder X-ray diffraction and N 2 adsorption-desorption analysis of the derivatized material confirmed that the textural properties of the hexagonally ordered host were preserved during the grafting experiment and that the channels remained accessible, despite reductions in surface area and pore volume. The derivatized material was also characterized by thermogravimetric analysis and vibrational spectroscopy.

AB - The acetonitrile complex [Mn(NCCH3)6] [B(C6F 5)4]2 has been immobilized in the ordered mesoporous silica MCM-41 functionalized with a pyrazolylpyridine (PP) ligand. A metal loading of 0.72 wt.% (0.13mmolg-1) was achieved. Powder X-ray diffraction and N 2 adsorption-desorption analysis of the derivatized material confirmed that the textural properties of the hexagonally ordered host were preserved during the grafting experiment and that the channels remained accessible, despite reductions in surface area and pore volume. The derivatized material was also characterized by thermogravimetric analysis and vibrational spectroscopy.

KW - Acetonitrile complexes

KW - Cationic polymerization

KW - Chelating ligands

KW - Immobilization

KW - Manganese

KW - Mesoporous materials

UR - https://www.scopus.com/pages/publications/7944228680

U2 - 10.1016/j.micromeso.2004.08.006

DO - 10.1016/j.micromeso.2004.08.006

M3 - Article

AN - SCOPUS:7944228680

SN - 1387-1811

VL - 76

SP - 131

EP - 136

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this