Synthesis and characterisation of ring-substituted POCOP halide complexes of group 10 metals

Markus Joksch; Hemlata Agarwala; Julia Haak; Anke Spannenberg; Torsten Beweries

doi:10.1016/j.poly.2017.09.001

Synthesis and characterisation of ring-substituted POCOP halide complexes of group 10 metals

Markus Joksch
, Hemlata Agarwala
, Julia Haak
, Anke Spannenberg
, Torsten Beweries

Leibniz-Institut für Katalyse

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The synthesis and full characterisation of a series of ring-substituted ^t^BuPOCOP^t^Bu halide complexes of group 10 metals [3,5-R₂(^t^BuPOCOP^t^Bu)MX] (3,5-R₂(^t^BuPOCOP^t^Bu) = κ³-C₅HR₂-2,6-(OPtBu₂)₂ with R = tBu, COOMe; X = Cl, I; M = Ni, Pd, Pt) are described. The structure of all complexes was confirmed by X-ray crystal structure analysis. DFT analysis to evaluate the electronic influence of the tBu and COOMe substituents was performed.

Original language	English
Pages (from-to)	118-125
Number of pages	8
Journal	Polyhedron
Volume	143
DOIs	https://doi.org/10.1016/j.poly.2017.09.001
State	Published - 15 Mar 2018
Externally published	Yes

Keywords

DFT calculations
Nickel
Palladium
Pincer ligands
Platinum

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title = "Synthesis and characterisation of ring-substituted POCOP halide complexes of group 10 metals",

abstract = "The synthesis and full characterisation of a series of ring-substituted tBuPOCOPtBu halide complexes of group 10 metals [3,5-R2(tBuPOCOPtBu)MX] (3,5-R2(tBuPOCOPtBu) = κ3-C5HR2-2,6-(OPtBu2)2 with R = tBu, COOMe; X = Cl, I; M = Ni, Pd, Pt) are described. The structure of all complexes was confirmed by X-ray crystal structure analysis. DFT analysis to evaluate the electronic influence of the tBu and COOMe substituents was performed.",

keywords = "DFT calculations, Nickel, Palladium, Pincer ligands, Platinum",

author = "Markus Joksch and Hemlata Agarwala and Julia Haak and Anke Spannenberg and Torsten Beweries",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2018",

month = mar,

day = "15",

doi = "10.1016/j.poly.2017.09.001",

language = "English",

volume = "143",

pages = "118--125",

journal = "Polyhedron",

issn = "0277-5387",

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TY - JOUR

T1 - Synthesis and characterisation of ring-substituted POCOP halide complexes of group 10 metals

AU - Joksch, Markus

AU - Agarwala, Hemlata

AU - Haak, Julia

AU - Spannenberg, Anke

AU - Beweries, Torsten

PY - 2018/3/15

Y1 - 2018/3/15

N2 - The synthesis and full characterisation of a series of ring-substituted tBuPOCOPtBu halide complexes of group 10 metals [3,5-R2(tBuPOCOPtBu)MX] (3,5-R2(tBuPOCOPtBu) = κ3-C5HR2-2,6-(OPtBu2)2 with R = tBu, COOMe; X = Cl, I; M = Ni, Pd, Pt) are described. The structure of all complexes was confirmed by X-ray crystal structure analysis. DFT analysis to evaluate the electronic influence of the tBu and COOMe substituents was performed.

AB - The synthesis and full characterisation of a series of ring-substituted tBuPOCOPtBu halide complexes of group 10 metals [3,5-R2(tBuPOCOPtBu)MX] (3,5-R2(tBuPOCOPtBu) = κ3-C5HR2-2,6-(OPtBu2)2 with R = tBu, COOMe; X = Cl, I; M = Ni, Pd, Pt) are described. The structure of all complexes was confirmed by X-ray crystal structure analysis. DFT analysis to evaluate the electronic influence of the tBu and COOMe substituents was performed.

KW - DFT calculations

KW - Nickel

KW - Palladium

KW - Pincer ligands

KW - Platinum

UR - https://www.scopus.com/pages/publications/85029677061

U2 - 10.1016/j.poly.2017.09.001

DO - 10.1016/j.poly.2017.09.001

M3 - Article

AN - SCOPUS:85029677061

SN - 0277-5387

VL - 143

SP - 118

EP - 125

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis and characterisation of ring-substituted POCOP halide complexes of group 10 metals

Abstract

Keywords

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