Synthese von 4,4‐Bis(trifluormethyl)‐1‐oxabuta‐1,3‐dienen

Klaus Burger, Brigitte Helmreich

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Synthesis of 4,4‐Bis(trifluoromethyl)‐1‐oxabuta‐1,3‐dienes Silyl enol ethers 1 and hexafluoroacetone 2 react to give O‐silylated aldol adducts 3 which, after desilylation with methanol/hydrochloric acid, are transformed into 4.4‐bis(trifluoromethyl)‐1‐oxabuta‐1,3‐dienes 5 on treatment with trifluoroacetic acid anhydride/pyridine.

Original languageGerman
Pages (from-to)219-226
Number of pages8
JournalJournal fur Praktische Chemie - Chemiker - Zeitung
Volume334
Issue number3
DOIs
StatePublished - 1992

Cite this