Symmetrical bis-(NHC) palladium(II) complexes: Synthesis, structure, and application in catalysis

Nadežda B. Jokić, Claudia S. Straubinger, Serena Li Min Goh, Eberhardt Herdtweck, Wolfgang A. Herrmann, Fritz E. Kühn

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

The synthesis and characterization of symmetrically substituted bis-N-heterocyclic carbene palladium(II) complexes with a functional group attached to the bridging moiety is described, as well as the immobilization of one of them on polystyrene Wang resin. The resulting complexes were tested both in homogeneous and heterogeneous Suzuki-Miyaura cross-coupling reactions.

Original languageEnglish
Pages (from-to)4181-4188
Number of pages8
JournalInorganica Chimica Acta
Volume363
Issue number15
DOIs
StatePublished - 10 Dec 2010

Keywords

  • Catalysis
  • N-heterocyclic carbenes
  • Palladium
  • Polymer-supported catalyst
  • Suzuki-Miyaura reaction

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