Abstract
The spectrum of the velocity-autocorrelation function at small frequencies is evaluated within mode-coupling theory for liquid argon at the triple point and for liquid rubidium. We investigate the dynamical processes limiting the asymptotic range over which the low-frequency square-root cusp of the spectrum can be observed. The frequency dependence of the shear viscosity is shown to have the largest effect upon the suppression of the anomalous long-time decay of velocity correlations. Our results indicate that in the high-density fluids considered the above anomaly shows up only as a percent contribution to the spectrum below some 1011 sec-1.
Original language | English |
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Pages (from-to) | 1603-1607 |
Number of pages | 5 |
Journal | Physical Review A |
Volume | 20 |
Issue number | 4 |
DOIs | |
State | Published - 1979 |