Suppression of Deactivation Processes in Photocatalytic Reduction of CO₂ Using Pulsed Light

The one-electron-reduced (OER) species of rhenium-based catalysts in the homogeneous photocatalytic reduction of CO₂ represents the starting point of light-induced deactivation processes, which lead to low catalyst activity and productivity. Herein, we report the suppression of these processes using pulsed light. Experimental parameters to avoid the irradiation of the OER species were estimated, leading us to conclude that pulse lengths shorter than 1 ns and repetition rates lower than 33 Hz should be employed. [Re(bpy)(CO)₃X] (bpy=2,2′-bipyridine; X=Cl (1), Br (3)) catalysts were employed in pulsed irradiation experiments using different light sources, pulse lengths and repetition rates. Pulsed irradiation experiments using LEDs revealed that a minimum average photon flux is necessary to enable CO₂ conversion. Furthermore, pulsed laser light with a 10 ns pulse length partially prevented lightinduced deactivation processes, whereas efficient suppression was achieved using a 30 ps pulse length.