1H, 13C, 29Si-NMR and 35,37Cl NQR Spectra of (Chloromethyl)silane, H3SiCH2Cl

Hubert Schmidbaur, Beate Zimmer, F. H. Köhler, Wolfgang Buchner

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

1H-, 13C-, 29Si-NMR- und 35,37Cl NQR spectra have been obtained for (chloromethyl)silane, H3SiCH2Cl. The results are compared with the corresponding parameters of ethyl chloride, H3CCH2Cl. A less polar C-Cl bond is found in the Silicon Compound, due to the electronic effect of the silyl group H3Si. Previous findings are in agreement with this conclusion.

Original languageEnglish
Pages (from-to)481-484
Number of pages4
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume32
Issue number5
DOIs
StatePublished - May 1977
Externally publishedYes

Keywords

  • (Chloromethyl)silane
  • NMR
  • NQR
  • Silanes

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