Subpicosecond vibrational relaxation in Ca2 in rare gas solids

V. E. Bondybey; Carolyn Albiston

doi:10.1063/1.436162

Subpicosecond vibrational relaxation in Ca₂ in rare gas solids

V. E. Bondybey, Carolyn Albiston

Alcatel-Lucent

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The ground state vibrational levels of Ca₂ exhibit broadening due to fast vibrational relaxation. The relaxation in the upper state is considerably slower and in krypton extensive unrelaxed emission is observed. The Ca₂ molecular potential and vibrational constants exhibit large matrix shifts due to interaction with the lattice.

Original language	English
Pages (from-to)	3172-3176
Number of pages	5
Journal	Journal of Chemical Physics
Volume	68
Issue number	7
DOIs	https://doi.org/10.1063/1.436162
State	Published - 1978
Externally published	Yes

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title = "Subpicosecond vibrational relaxation in Ca2 in rare gas solids",

abstract = "The ground state vibrational levels of Ca2 exhibit broadening due to fast vibrational relaxation. The relaxation in the upper state is considerably slower and in krypton extensive unrelaxed emission is observed. The Ca2 molecular potential and vibrational constants exhibit large matrix shifts due to interaction with the lattice.",

author = "Bondybey, {V. E.} and Carolyn Albiston",

year = "1978",

doi = "10.1063/1.436162",

language = "English",

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journal = "Journal of Chemical Physics",

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AU - Bondybey, V. E.

AU - Albiston, Carolyn

PY - 1978

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N2 - The ground state vibrational levels of Ca2 exhibit broadening due to fast vibrational relaxation. The relaxation in the upper state is considerably slower and in krypton extensive unrelaxed emission is observed. The Ca2 molecular potential and vibrational constants exhibit large matrix shifts due to interaction with the lattice.

AB - The ground state vibrational levels of Ca2 exhibit broadening due to fast vibrational relaxation. The relaxation in the upper state is considerably slower and in krypton extensive unrelaxed emission is observed. The Ca2 molecular potential and vibrational constants exhibit large matrix shifts due to interaction with the lattice.

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U2 - 10.1063/1.436162

DO - 10.1063/1.436162

M3 - Article

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VL - 68

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EP - 3176

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 7

ER -

Subpicosecond vibrational relaxation in Ca₂ in rare gas solids

Abstract

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