TY - JOUR
T1 - Structure and catalytic activity of the ruthenium(I) sawhorse-type complex [Ru2{μ,η2-CF3(CF2) 5COO}2(DMSO)2(CO)4]
AU - Zimmermann, Teresa K.
AU - Haslinger, Stefan
AU - Pöthig, Alexander
AU - Kühn, Fritz E.
PY - 2014/4
Y1 - 2014/4
N2 - The title compound, cis-di-μ-perfluoroheptanoato-κ4 O:O'-bis[dicarbonyl(dimethyl sulfoxide-κS)ruthenium(I)](Ru - Ru), [Ru 2(C7F13O2)2(C 2H6OS)2(CO)4], is a sawhorse-type dinuclear ruthenium complex with two bridging perfluoroheptanoate ligands, and with two dimethyl sulfoxide (DMSO) ligands in the axial positions coordinating via the S atoms. It is a new example of a compound with an aliphatic fluorinated carboxylate ligand. The Ru - Ru bond distance of 2.6908(3)Å indicates a direct Ru - Ru interaction. The compound is an active catalyst in transvinylation of propionic acid with vinyl acetate.
AB - The title compound, cis-di-μ-perfluoroheptanoato-κ4 O:O'-bis[dicarbonyl(dimethyl sulfoxide-κS)ruthenium(I)](Ru - Ru), [Ru 2(C7F13O2)2(C 2H6OS)2(CO)4], is a sawhorse-type dinuclear ruthenium complex with two bridging perfluoroheptanoate ligands, and with two dimethyl sulfoxide (DMSO) ligands in the axial positions coordinating via the S atoms. It is a new example of a compound with an aliphatic fluorinated carboxylate ligand. The Ru - Ru bond distance of 2.6908(3)Å indicates a direct Ru - Ru interaction. The compound is an active catalyst in transvinylation of propionic acid with vinyl acetate.
KW - catalytic investigation
KW - crystal structure
KW - perfluoroheptanoate
KW - Ru - Ru bond
KW - ruthenium(I) sawhorse-type complexes
KW - transvinylation catalyst
UR - http://www.scopus.com/inward/record.url?scp=84905446120&partnerID=8YFLogxK
U2 - 10.1107/S2053229614006354
DO - 10.1107/S2053229614006354
M3 - Article
AN - SCOPUS:84905446120
SN - 2053-2296
VL - 70
SP - 384
EP - 387
JO - Acta Crystallographica Section C: Structural Chemistry
JF - Acta Crystallographica Section C: Structural Chemistry
IS - 4
ER -