Structural relaxation in a viscous liquid studied by quasielastic nuclear forward scattering

I. Sergueev, H. Franz, T. Asthalter, W. Petry, U. van Bürck, G. V. Smirnov

Research output: Contribution to journalArticlepeer-review

Abstract

Quasielastic nuclear forward scattering (QNFS) of synchrotron radiation is employed as a probe of slow glass dynamics, in particular for the determination of the stretching parameter (formula presented) in the Kohlrausch-Williams-Watts relaxation function. The influence of this type of relaxation on multiple scattering is investigated in detail, and experimental results on the dynamics of the molecular glass former ferrocene/dibutylphthalate in the undercooled viscous state are presented. We observe a temperature independent stretching parameter of 0.47(2). Fitting the high temperature breakdown of the Lamb-Mössbauer factor with a square root dependence we obtain a mode-coupling critical temperature of (formula presented).

Original languageEnglish
Pages (from-to)1-8
Number of pages8
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume66
Issue number18
DOIs
StatePublished - 2002

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