Structural evolution of aragonite superstructures obtained in the presence of the siderophore deferoxamine

Marc Georg Willinger, Julien Polleux, Markus Antonietti, Helmut Cölfen, Nicola Pinna, Nadine Nassif

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

The effect of amphoteric siderophore deferoxamine on the crystallization behavior of calcium carbonate was investigated under bioinspired conditions. Amphoteric siderophore deferoxamine possesses self-organization ability, surface activity and ion-chelating properties. It induces in the present case the formation of unusual, highly organized aragonite mesocrystals during the precipitation of calcium carbonate from liquid phase. A detailed investigation of the structure and growth of the particles provides an insight into the role of the deferoxamine and its function in the crystallization process.

Original languageEnglish
Pages (from-to)3927-3935
Number of pages9
JournalCrystEngComm
Volume17
Issue number21
DOIs
StatePublished - 7 Jun 2015
Externally publishedYes

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