Structural complexity in intermetallic alloys: Long-periodic order beyond 10 nm in the system BaSn3/BaBi3

Siméon Ponou; Thomas F. Fässler; Lorenz Kienle

doi:10.1002/anie.200800378

Structural complexity in intermetallic alloys: Long-periodic order beyond 10 nm in the system BaSn₃/BaBi₃

Siméon Ponou, Thomas F. Fässler, Lorenz Kienle

Chair of Inorganic Chemistry with Focus on New Materials

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

(Figure Presented) Nanosized long-periodic stacking sequences are formed by polytypic transformations that are initiated by partially substituting Bi for Sn in the close-packed structure of BaSn₃. Single-crystal X-ray diffraction and TEM investigations show that temperature-dependent interlayer-ordering processes lead to repeat units beyond 10 nm (see TEM image).

Original language	English
Pages (from-to)	3999-4004
Number of pages	6
Journal	Angewandte Chemie International Edition in English
Volume	47
Issue number	21
DOIs	https://doi.org/10.1002/anie.200800378
State	Published - 13 May 2008

Keywords

Crystallography
Intermetallic phases
Solid-state structures
Stannide
X-ray diffraction

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10.1002/anie.200800378

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abstract = "(Figure Presented) Nanosized long-periodic stacking sequences are formed by polytypic transformations that are initiated by partially substituting Bi for Sn in the close-packed structure of BaSn3. Single-crystal X-ray diffraction and TEM investigations show that temperature-dependent interlayer-ordering processes lead to repeat units beyond 10 nm (see TEM image).",

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AU - Fässler, Thomas F.

AU - Kienle, Lorenz

PY - 2008/5/13

Y1 - 2008/5/13

N2 - (Figure Presented) Nanosized long-periodic stacking sequences are formed by polytypic transformations that are initiated by partially substituting Bi for Sn in the close-packed structure of BaSn3. Single-crystal X-ray diffraction and TEM investigations show that temperature-dependent interlayer-ordering processes lead to repeat units beyond 10 nm (see TEM image).

AB - (Figure Presented) Nanosized long-periodic stacking sequences are formed by polytypic transformations that are initiated by partially substituting Bi for Sn in the close-packed structure of BaSn3. Single-crystal X-ray diffraction and TEM investigations show that temperature-dependent interlayer-ordering processes lead to repeat units beyond 10 nm (see TEM image).

KW - Crystallography

KW - Intermetallic phases

KW - Solid-state structures

KW - Stannide

KW - X-ray diffraction

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Structural complexity in intermetallic alloys: Long-periodic order beyond 10 nm in the system BaSn₃/BaBi₃

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Keywords

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