Strong correlation effects in the ionisation of CS2

J. Schirmer, W. Domcke, L. S. Cederbaum, W. von Niessen, L. Åsbrink

Research output: Contribution to journalArticlepeer-review

63 Scopus citations

Abstract

The Hell photoelectron spectrum of CS2 is presented. This spectrum is investigated by two different Green's function calculations. For the outer valence region the origin and assignment of satellite lines of significant intensity is clarified. Strong final state correlation effects are found for the inner valence region showing the so-called breakdown of single-particle picture of ionisation.

Original languageEnglish
Pages (from-to)30-35
Number of pages6
JournalChemical Physics Letters
Volume61
Issue number1
DOIs
StatePublished - 1 Feb 1979
Externally publishedYes

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