Stretched poly(vinyl acetate) gels as NMR alignment media for the measurement of residual dipolar couplings in polar organic solvents

J. Christoph Freudenberger; Sebastian Knör; Kyryl Kobzar; Dominik Heckmann; Thomas Paululat; Horst Kessler; Burkhard Luy

doi:10.1002/anie.200461241

Stretched poly(vinyl acetate) gels as NMR alignment media for the measurement of residual dipolar couplings in polar organic solvents

J. Christoph Freudenberger
, Sebastian Knör
, Kyryl Kobzar
, Dominik Heckmann
, Thomas Paululat
, Horst Kessler
, Burkhard Luy

TUM Emeriti of Excellence

Research output: Contribution to journal › Article › peer-review

80 Scopus citations

Abstract

Partial alignment of molecules in polar organic solvents for the measurement of residual dipolar couplings (RDCs) in high-resolution NMR spectroscopy can be achieved by stretched poly(vinyl acetate) gels. The method opens the door of RDC-derived structural information (e.g. from D_CH couplings, see picture) to new classes of molecules by closing the existing gap between apolar and aqueous solutions. (Figure Presented).

Original language	English
Pages (from-to)	423-426
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	44
Issue number	3
DOIs	https://doi.org/10.1002/anie.200461241
State	Published - 3 Jan 2005

Keywords

Gels
NMR spectroscopy
Partial alignment
Residual dipolar coupling

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10.1002/anie.200461241

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title = "Stretched poly(vinyl acetate) gels as NMR alignment media for the measurement of residual dipolar couplings in polar organic solvents",

abstract = "Partial alignment of molecules in polar organic solvents for the measurement of residual dipolar couplings (RDCs) in high-resolution NMR spectroscopy can be achieved by stretched poly(vinyl acetate) gels. The method opens the door of RDC-derived structural information (e.g. from DCH couplings, see picture) to new classes of molecules by closing the existing gap between apolar and aqueous solutions. (Figure Presented).",

keywords = "Gels, NMR spectroscopy, Partial alignment, Residual dipolar coupling",

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AU - Freudenberger, J. Christoph

AU - Knör, Sebastian

AU - Kobzar, Kyryl

AU - Heckmann, Dominik

AU - Paululat, Thomas

AU - Kessler, Horst

AU - Luy, Burkhard

PY - 2005/1/3

Y1 - 2005/1/3

N2 - Partial alignment of molecules in polar organic solvents for the measurement of residual dipolar couplings (RDCs) in high-resolution NMR spectroscopy can be achieved by stretched poly(vinyl acetate) gels. The method opens the door of RDC-derived structural information (e.g. from DCH couplings, see picture) to new classes of molecules by closing the existing gap between apolar and aqueous solutions. (Figure Presented).

AB - Partial alignment of molecules in polar organic solvents for the measurement of residual dipolar couplings (RDCs) in high-resolution NMR spectroscopy can be achieved by stretched poly(vinyl acetate) gels. The method opens the door of RDC-derived structural information (e.g. from DCH couplings, see picture) to new classes of molecules by closing the existing gap between apolar and aqueous solutions. (Figure Presented).

KW - Gels

KW - NMR spectroscopy

KW - Partial alignment

KW - Residual dipolar coupling

UR - https://www.scopus.com/pages/publications/12344302490

U2 - 10.1002/anie.200461241

DO - 10.1002/anie.200461241

M3 - Article

C2 - 15624159

AN - SCOPUS:12344302490

SN - 1433-7851

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 3

ER -

Stretched poly(vinyl acetate) gels as NMR alignment media for the measurement of residual dipolar couplings in polar organic solvents

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Keywords

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