Abstract
Partial alignment of molecules in polar organic solvents for the measurement of residual dipolar couplings (RDCs) in high-resolution NMR spectroscopy can be achieved by stretched poly(vinyl acetate) gels. The method opens the door of RDC-derived structural information (e.g. from DCH couplings, see picture) to new classes of molecules by closing the existing gap between apolar and aqueous solutions. (Figure Presented).
Original language | English |
---|---|
Pages (from-to) | 423-426 |
Number of pages | 4 |
Journal | Angewandte Chemie International Edition in English |
Volume | 44 |
Issue number | 3 |
DOIs | |
State | Published - 3 Jan 2005 |
Keywords
- Gels
- NMR spectroscopy
- Partial alignment
- Residual dipolar coupling