Stereochemical Course of the Generation of 3-Mercaptohexanal and 3-Mercaptohexanol by β-Lyase-Catalyzed Cleavage of Cysteine Conjugates

Keyphrases

• Lyase 100%
• 3-mercaptohexanol 100%
• Stereochemical Hypothesis 100%
• Cysteine Conjugates 100%
• Tryptophanase 66%
• Eubacterium Limosum 66%
• Escherichia Coli 33%
• Two-source 33%
• N-acetylation 33%
• Enantioselectivity 33%
• In Situ Generation 33%
• Cysteine 33%
• Hexanal 33%
• (E)-2-hexenal 33%
• Enzyme Preparation 33%
• Conversion Rate 33%
• 1,3-thiazolidine 33%
• Thiazolidine-4-carboxylic Acid 33%
• Acylase 33%
• Crude Enzyme Extract 33%

Chemistry

• 3-Mercaptohexanol 100%
• Cysteine 100%
• formation 66%
• Acetyl 33%
• Enantioselectivity 33%
• L-Cysteine 33%
• 1,3-thiazolidine 33%
• 2-Hexenal 33%
• Diastereoisomeric Mixture 33%
• S-Conjugate 33%
• Hexanal 33%
• Enantiomer 33%
• Carboxylic Acid 33%