Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces

Mikhail Meilikhov; Kirill Yusenko; Eckhardt Schollmeyer; Christian Mayer; Hans Jürgen Buschmann; Roland A. Fischer

doi:10.1039/c0dt01820a

Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces

Mikhail Meilikhov
, Kirill Yusenko
, Eckhardt Schollmeyer
, Christian Mayer
, Hans Jürgen Buschmann
, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung
Deutsches Textilforschungszentrum Nord-West
University of Duisburg-Essen

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

Thin films of [Cu₃(btc)₂]_n (btc = 1,3,5-benzenetricarboxylate) metal organic framework were deposited in a stepwise manner on surfaces of flexible organic polymers. The thickness of films can be precisely controlled. The deposition of the first cycles was monitored by UV-vis spectroscopy. The porosity was proven by the adsorption of pyrazine, which was monitored by FT-IR and thermogravimetric analysis. The deposition of MOF thin films on flexible polymer surfaces might be a new path for the fabrication of functional materials for different applications, such as protection layers for working clothes and gas separation materials in the textile industry.

Original language	English
Pages (from-to)	4838-4841
Number of pages	4
Journal	Dalton Transactions
Volume	40
Issue number	18
DOIs	https://doi.org/10.1039/c0dt01820a
State	Published - 14 May 2011
Externally published	Yes

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title = "Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces",

abstract = "Thin films of [Cu3(btc)2]n (btc = 1,3,5-benzenetricarboxylate) metal organic framework were deposited in a stepwise manner on surfaces of flexible organic polymers. The thickness of films can be precisely controlled. The deposition of the first cycles was monitored by UV-vis spectroscopy. The porosity was proven by the adsorption of pyrazine, which was monitored by FT-IR and thermogravimetric analysis. The deposition of MOF thin films on flexible polymer surfaces might be a new path for the fabrication of functional materials for different applications, such as protection layers for working clothes and gas separation materials in the textile industry.",

author = "Mikhail Meilikhov and Kirill Yusenko and Eckhardt Schollmeyer and Christian Mayer and Buschmann, \{Hans J{\"u}rgen\} and Fischer, \{Roland A.\}",

year = "2011",

month = may,

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doi = "10.1039/c0dt01820a",

language = "English",

volume = "40",

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T1 - Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces

AU - Meilikhov, Mikhail

AU - Yusenko, Kirill

AU - Schollmeyer, Eckhardt

AU - Mayer, Christian

AU - Buschmann, Hans Jürgen

AU - Fischer, Roland A.

PY - 2011/5/14

Y1 - 2011/5/14

N2 - Thin films of [Cu3(btc)2]n (btc = 1,3,5-benzenetricarboxylate) metal organic framework were deposited in a stepwise manner on surfaces of flexible organic polymers. The thickness of films can be precisely controlled. The deposition of the first cycles was monitored by UV-vis spectroscopy. The porosity was proven by the adsorption of pyrazine, which was monitored by FT-IR and thermogravimetric analysis. The deposition of MOF thin films on flexible polymer surfaces might be a new path for the fabrication of functional materials for different applications, such as protection layers for working clothes and gas separation materials in the textile industry.

AB - Thin films of [Cu3(btc)2]n (btc = 1,3,5-benzenetricarboxylate) metal organic framework were deposited in a stepwise manner on surfaces of flexible organic polymers. The thickness of films can be precisely controlled. The deposition of the first cycles was monitored by UV-vis spectroscopy. The porosity was proven by the adsorption of pyrazine, which was monitored by FT-IR and thermogravimetric analysis. The deposition of MOF thin films on flexible polymer surfaces might be a new path for the fabrication of functional materials for different applications, such as protection layers for working clothes and gas separation materials in the textile industry.

UR - https://www.scopus.com/pages/publications/79955037661

U2 - 10.1039/c0dt01820a

DO - 10.1039/c0dt01820a

M3 - Article

AN - SCOPUS:79955037661

SN - 1477-9226

VL - 40

SP - 4838

EP - 4841

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces

Abstract

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