Spectroscopy of carbendazim in the UV region by resonant multiphoton ionisation

B. Bescós; J. M. Orea; C. Montero; A. González Ureña; R. Weinkauf; U. Boesl; E. W. Schlag

doi:10.1016/S0009-2614(98)00173-0

Spectroscopy of carbendazim in the UV region by resonant multiphoton ionisation

B. Bescós
, J. M. Orea
, C. Montero
, A. González Ureña
, R. Weinkauf
, U. Boesl
, E. W. Schlag

Natural Sciences

Universidad Complutense de Madrid Instituto Pluridisciplinar
Technical University of Munich

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The spectroscopic characterisation of carbendazim (methyl 2-benzimidazolecarbamate) has been carried out by combining laser desorption (LD) with resonance-enhanced multiphoton ionization (REMPI) followed by time-of-flight mass spectrometry (TOFMS) detection. After optimization of the experimental conditions, the REMPI spectrum of carbendazim was obtained in the region between 280 and 283 nm, with the (0,0) band and Δv=0 sequence structure at 281.1±0.2 nm. The spectrum exhibits a sequence of peaks separated by approximately 69 cm^-1, consistent with the presence of a low-energy vibration in the ground electronic state. This result is of value in facilitating the development of a direct and sensitive analytical method for the determination of carbendazim in a given sample by LD-REMPI-TOFMS.

Original language	English
Pages (from-to)	371-378
Number of pages	8
Journal	Chemical Physics Letters
Volume	287
Issue number	3-4
DOIs	https://doi.org/10.1016/S0009-2614(98)00173-0
State	Published - 1 May 1998

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@article{7b030e09a771496fb31bd8917ba5c8fb,

title = "Spectroscopy of carbendazim in the UV region by resonant multiphoton ionisation",

abstract = "The spectroscopic characterisation of carbendazim (methyl 2-benzimidazolecarbamate) has been carried out by combining laser desorption (LD) with resonance-enhanced multiphoton ionization (REMPI) followed by time-of-flight mass spectrometry (TOFMS) detection. After optimization of the experimental conditions, the REMPI spectrum of carbendazim was obtained in the region between 280 and 283 nm, with the (0,0) band and Δv=0 sequence structure at 281.1±0.2 nm. The spectrum exhibits a sequence of peaks separated by approximately 69 cm-1, consistent with the presence of a low-energy vibration in the ground electronic state. This result is of value in facilitating the development of a direct and sensitive analytical method for the determination of carbendazim in a given sample by LD-REMPI-TOFMS.",

author = "B. Besc{\'o}s and Orea, \{J. M.\} and C. Montero and \{Gonz{\'a}lez Ure{\~n}a\}, A. and R. Weinkauf and U. Boesl and Schlag, \{E. W.\}",

note = "Funding Information: This work received financial support from the DGICYT of Spain Grant No. PB95/391 and the Comunidad Aut{\'o}noma de Madrid Grant No. 06M/058/96. BB thanks the Ministerio de Educaci{\'o}n y Cultura of Spain for her fellowship. JMO acknowledges his postdoctoral contract to the Ministerio de Educaci{\'o}n y Cultura of Spain. ",

year = "1998",

month = may,

day = "1",

doi = "10.1016/S0009-2614(98)00173-0",

language = "English",

volume = "287",

pages = "371--378",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "3-4",

}

TY - JOUR

T1 - Spectroscopy of carbendazim in the UV region by resonant multiphoton ionisation

AU - Bescós, B.

AU - Orea, J. M.

AU - Montero, C.

AU - González Ureña, A.

AU - Weinkauf, R.

AU - Boesl, U.

AU - Schlag, E. W.

N1 - Funding Information: This work received financial support from the DGICYT of Spain Grant No. PB95/391 and the Comunidad Autónoma de Madrid Grant No. 06M/058/96. BB thanks the Ministerio de Educación y Cultura of Spain for her fellowship. JMO acknowledges his postdoctoral contract to the Ministerio de Educación y Cultura of Spain.

PY - 1998/5/1

Y1 - 1998/5/1

N2 - The spectroscopic characterisation of carbendazim (methyl 2-benzimidazolecarbamate) has been carried out by combining laser desorption (LD) with resonance-enhanced multiphoton ionization (REMPI) followed by time-of-flight mass spectrometry (TOFMS) detection. After optimization of the experimental conditions, the REMPI spectrum of carbendazim was obtained in the region between 280 and 283 nm, with the (0,0) band and Δv=0 sequence structure at 281.1±0.2 nm. The spectrum exhibits a sequence of peaks separated by approximately 69 cm-1, consistent with the presence of a low-energy vibration in the ground electronic state. This result is of value in facilitating the development of a direct and sensitive analytical method for the determination of carbendazim in a given sample by LD-REMPI-TOFMS.

AB - The spectroscopic characterisation of carbendazim (methyl 2-benzimidazolecarbamate) has been carried out by combining laser desorption (LD) with resonance-enhanced multiphoton ionization (REMPI) followed by time-of-flight mass spectrometry (TOFMS) detection. After optimization of the experimental conditions, the REMPI spectrum of carbendazim was obtained in the region between 280 and 283 nm, with the (0,0) band and Δv=0 sequence structure at 281.1±0.2 nm. The spectrum exhibits a sequence of peaks separated by approximately 69 cm-1, consistent with the presence of a low-energy vibration in the ground electronic state. This result is of value in facilitating the development of a direct and sensitive analytical method for the determination of carbendazim in a given sample by LD-REMPI-TOFMS.

UR - https://www.scopus.com/pages/publications/0032067454

U2 - 10.1016/S0009-2614(98)00173-0

DO - 10.1016/S0009-2614(98)00173-0

M3 - Article

AN - SCOPUS:0032067454

SN - 0009-2614

VL - 287

SP - 371

EP - 378

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

ER -

Spectroscopy of carbendazim in the UV region by resonant multiphoton ionisation

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