Spectral holes as probes for structural transitions in polymers

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Abstract

We show how narrow spectral holes burnt into the inhomogeneous absorption of dye doped polymers can be used as extremely sensitive detectors for measuring structural rearrangement processes. A model is suggested which relates the observed hole burning phenomena to the specific heat of the conformation phase space.

Original languageEnglish
Pages (from-to)115-122
Number of pages8
JournalDie Angewandte Makromolekulare Chemie
Volume183
Issue number1
DOIs
StatePublished - Dec 1990
Externally publishedYes

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