Sonolysis and radiolysis of glyceraldehyde in deaerated aqueous solution

Eva Fuchs; Helmut Heusinger

doi:10.1016/1350-4177(94)00014-J

Sonolysis and radiolysis of glyceraldehyde in deaerated aqueous solution

Eva Fuchs, Helmut Heusinger

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Technical University of Munich

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8 Scopus citations

Abstract

The objective of this work was to contribute to the mechanism of the sonolytic and radiolytic reactions leading in deaerated aqueous solutions of sugars to products by radical-radical combination. For this purpose glyceraldehyde, the first homologue of the series of aldoses, was investigated. Primary glyceraldehyde radicals are produced by abstraction of carbon-bonded hydrogen atoms by sonolytic or radiolytic H and OH radicals. Secondary glyceraldehyde radicals are derived from primary radicals by elimination of water. Both kinds of radicals were found to participate in dimer production.

Original language	English
Pages (from-to)	S105-S109
Journal	Ultrasonics Sonochemistry
Volume	2
Issue number	2
DOIs	https://doi.org/10.1016/1350-4177(94)00014-J
State	Published - 1995

Keywords

glyceraldehyde
radiolysis
sonolysis

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10.1016/1350-4177(94)00014-J

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title = "Sonolysis and radiolysis of glyceraldehyde in deaerated aqueous solution",

abstract = "The objective of this work was to contribute to the mechanism of the sonolytic and radiolytic reactions leading in deaerated aqueous solutions of sugars to products by radical-radical combination. For this purpose glyceraldehyde, the first homologue of the series of aldoses, was investigated. Primary glyceraldehyde radicals are produced by abstraction of carbon-bonded hydrogen atoms by sonolytic or radiolytic H and OH radicals. Secondary glyceraldehyde radicals are derived from primary radicals by elimination of water. Both kinds of radicals were found to participate in dimer production.",

keywords = "glyceraldehyde, radiolysis, sonolysis",

author = "Eva Fuchs and Helmut Heusinger",

note = "Funding Information: This work was supported by the Deutsche ForschungsgemeinschWafet. thank Mr. B. Gruhn for assistancwe ith the masss pectrometry.",

year = "1995",

doi = "10.1016/1350-4177(94)00014-J",

language = "English",

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journal = "Ultrasonics Sonochemistry",

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TY - JOUR

T1 - Sonolysis and radiolysis of glyceraldehyde in deaerated aqueous solution

AU - Fuchs, Eva

AU - Heusinger, Helmut

N1 - Funding Information: This work was supported by the Deutsche ForschungsgemeinschWafet. thank Mr. B. Gruhn for assistancwe ith the masss pectrometry.

PY - 1995

Y1 - 1995

N2 - The objective of this work was to contribute to the mechanism of the sonolytic and radiolytic reactions leading in deaerated aqueous solutions of sugars to products by radical-radical combination. For this purpose glyceraldehyde, the first homologue of the series of aldoses, was investigated. Primary glyceraldehyde radicals are produced by abstraction of carbon-bonded hydrogen atoms by sonolytic or radiolytic H and OH radicals. Secondary glyceraldehyde radicals are derived from primary radicals by elimination of water. Both kinds of radicals were found to participate in dimer production.

AB - The objective of this work was to contribute to the mechanism of the sonolytic and radiolytic reactions leading in deaerated aqueous solutions of sugars to products by radical-radical combination. For this purpose glyceraldehyde, the first homologue of the series of aldoses, was investigated. Primary glyceraldehyde radicals are produced by abstraction of carbon-bonded hydrogen atoms by sonolytic or radiolytic H and OH radicals. Secondary glyceraldehyde radicals are derived from primary radicals by elimination of water. Both kinds of radicals were found to participate in dimer production.

KW - glyceraldehyde

KW - radiolysis

KW - sonolysis

UR - http://www.scopus.com/inward/record.url?scp=0009015179&partnerID=8YFLogxK

U2 - 10.1016/1350-4177(94)00014-J

DO - 10.1016/1350-4177(94)00014-J

M3 - Article

AN - SCOPUS:0009015179

SN - 1350-4177

VL - 2

SP - S105-S109

JO - Ultrasonics Sonochemistry

JF - Ultrasonics Sonochemistry

IS - 2

ER -

Sonolysis and radiolysis of glyceraldehyde in deaerated aqueous solution

Abstract

Keywords

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