TY - JOUR
T1 - Solvent‐Free Volatile Alkoxides of the Alkaline‐Earth Elements
AU - Herrmann, Wolfgang A.
AU - Huber, Norbert W.
AU - Priermeier, Thomas
PY - 1994/1/17
Y1 - 1994/1/17
N2 - At low temperatures and without decomposition, alkaline‐earth alkoxides 1 (M = Ca, Sr, Ba) and an analogous cadmium complex sublime under vacuum, which makes these compounds possible candidates for chemical vapor deposition (CVD) techniques, for example, for the preparation of high‐temperature superconductors. The high volatility of these alkoxides is in part a consequence of their unusually low degree of aggregation. (Figure Presented.)
AB - At low temperatures and without decomposition, alkaline‐earth alkoxides 1 (M = Ca, Sr, Ba) and an analogous cadmium complex sublime under vacuum, which makes these compounds possible candidates for chemical vapor deposition (CVD) techniques, for example, for the preparation of high‐temperature superconductors. The high volatility of these alkoxides is in part a consequence of their unusually low degree of aggregation. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748231512&partnerID=8YFLogxK
U2 - 10.1002/anie.199401051
DO - 10.1002/anie.199401051
M3 - Article
AN - SCOPUS:33748231512
SN - 0570-0833
VL - 33
SP - 105
EP - 107
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 1
ER -