Solvent-Free Dinickelate [Ni{[CH2N(Me)]2CH2}Li2]2 with a Li4Ni2 Cluster Core via Nucleophilic Aminomethylation

Hans H. Karsch, Kai A. Schreiber, Manfred Reisky

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The doubly lithiated aminal bis(lithiomethyl-(methylamino))methane, [LiCH2N(Me)]2CH2, reacts with bis(trimethylphosphine)nickel dichloride in diethyl ether to give the solvent-free dinickelate [Ni{[CH2N(Me)]2-CH2}Li2]2 (1) in good yield. The molecular structure of 1 has been studied by X-ray-crystallography.

Original languageEnglish
Pages (from-to)3944-3946
Number of pages3
JournalOrganometallics
Volume18
Issue number19
DOIs
StatePublished - 13 Sep 1999

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