Soluble zintl phases A ₁₄ZnGe₁₆ (A = K, Rb) featuring [(η³-Ge₄)Zn(η²-Ge₄)] ^6- and [Ge₄]^4- clusters and the isolation of [(MesCu)₂(η³,η³-Ge₄)] ^4-

Keyphrases

• 18-crown-6 66%
• Alkali Metal Cations 33%
• Ammonia Solution 33%
• Anions 33%
• Band Structure Calculations 33%
• Chemical Reaction 33%
• Chemical Reactivity 33%
• Electron Localization Function 33%
• Electronic Structure 33%
• Endmember 33%
• Group 14 Elements 33%
• Heterometallic 33%
• Intermetallic Phases 33%
• K-18 33%
• Liquid Ammonia 33%
• Main Group Elements 33%
• Molecular Orbital 33%
• Polyanion 33%
• Polyhedral Clusters 33%
• Rare Example 33%
• Structural Characterization 33%
• Ternary Intermetallics 33%
• Tetrahedron 66%
• Tetrels 33%
• Zintl Anions 33%
• Zintl Compounds 33%
• Zintl Phases 100%

Chemistry

• 18-Crown-6 66%
• Alkali Metal Cation 33%
• Ammonia 33%
• Band Structure Calculations 33%
• Chemical Reactivity 33%
• Electron Localization 33%
• Electronic State 33%
• Intermetallic Compound 33%
• Main Group Element 33%
• Molecular Orbital 33%
• Polyanion 33%
• Table Salt 33%
• Zintl Phase 100%