TY - JOUR
T1 - Sodium tetraphenylborate as a phenylating agent for gold(I) complexes
AU - Sladek, Alexander
AU - Hofreiter, Stefan
AU - Paul, Martin
AU - Schmidbaur, Hubert
PY - 1995/10/4
Y1 - 1995/10/4
N2 - Phenyl[tri(tent-butyl)phosphine]gold(I) has been prepared from tris([tri(tert-butyl)phosphine]gold(1))oxonium tetrafluoroborate and sodium tetraphenylborate in ethanol at ambient temperature. The compound is also available from chloro[tri(tert-butyl)phosphine]gold(I) and phenyllithium in tetrahydrofuran. 1,4-Bis([phenylgold(l)]diphenylphosphinomethyl)benzene has been generated from the chloro complex 1,4-[(ClAu)Ph2PCH2]2C6H4 either with silver oxide and sodium tetraphenylborate or with phenyllithium. The compounds have been identified by their analytical and spectroscopic data, and their structures have been determined by single-crystal X-ray diffraction studies.
AB - Phenyl[tri(tent-butyl)phosphine]gold(I) has been prepared from tris([tri(tert-butyl)phosphine]gold(1))oxonium tetrafluoroborate and sodium tetraphenylborate in ethanol at ambient temperature. The compound is also available from chloro[tri(tert-butyl)phosphine]gold(I) and phenyllithium in tetrahydrofuran. 1,4-Bis([phenylgold(l)]diphenylphosphinomethyl)benzene has been generated from the chloro complex 1,4-[(ClAu)Ph2PCH2]2C6H4 either with silver oxide and sodium tetraphenylborate or with phenyllithium. The compounds have been identified by their analytical and spectroscopic data, and their structures have been determined by single-crystal X-ray diffraction studies.
KW - Phenylation
KW - Phenylgold(I) Complexes
KW - Tetraphenylborates as phenylating agents
UR - http://www.scopus.com/inward/record.url?scp=1842579990&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(95)05589-H
DO - 10.1016/0022-328X(95)05589-H
M3 - Article
AN - SCOPUS:1842579990
SN - 0022-328X
VL - 501
SP - 47
EP - 51
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -