[Sn9HgSn9]6-: An intermetalloid Zintl ion with two Sn9 connected by heteroatom

Li Yong; M. Bele Boeddinghaus; Thomas F. Fässler

doi:10.1002/zaac.201000103

[Sn₉HgSn₉]^6-: An intermetalloid Zintl ion with two Sn₉ connected by heteroatom

Li Yong
, M. Bele Boeddinghaus
, Thomas F. Fässler

Chair of Inorganic Chemistry with Focus on New Materials

University of Tennessee
Technical University of Munich

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The title compound [K([2,2,2]crypt)]₁₂[Sn₉] ₂[Sn₉HgSn₉] has been obtained by reaction of elemental mercury with the binary phase K₄Sn₉ in ethylenediamine after addition of [2,2,2]crypt and layering with toluene. The X-ray single crystal analysis shows that the compound consists of two isolated Sn₉ clusters and two Sn₉ clusters connected by a mercury atom.

Original language	English
Pages (from-to)	1293-1296
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	636
Issue number	7
DOIs	https://doi.org/10.1002/zaac.201000103
State	Published - Jul 2010

Keywords

Cluster compounds
Crystal structure
Mercury
Tin
Zintl ions

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title = "[Sn9HgSn9]6-: An intermetalloid Zintl ion with two Sn9 connected by heteroatom",

abstract = "The title compound [K([2,2,2]crypt)]12[Sn9] 2[Sn9HgSn9] has been obtained by reaction of elemental mercury with the binary phase K4Sn9 in ethylenediamine after addition of [2,2,2]crypt and layering with toluene. The X-ray single crystal analysis shows that the compound consists of two isolated Sn9 clusters and two Sn9 clusters connected by a mercury atom.",

keywords = "Cluster compounds, Crystal structure, Mercury, Tin, Zintl ions",

author = "Li Yong and Boeddinghaus, \{M. Bele\} and F{\"a}ssler, \{Thomas F.\}",

year = "2010",

month = jul,

doi = "10.1002/zaac.201000103",

language = "English",

volume = "636",

pages = "1293--1296",

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T1 - [Sn9HgSn9]6-

T2 - An intermetalloid Zintl ion with two Sn9 connected by heteroatom

AU - Yong, Li

AU - Boeddinghaus, M. Bele

AU - Fässler, Thomas F.

PY - 2010/7

Y1 - 2010/7

N2 - The title compound [K([2,2,2]crypt)]12[Sn9] 2[Sn9HgSn9] has been obtained by reaction of elemental mercury with the binary phase K4Sn9 in ethylenediamine after addition of [2,2,2]crypt and layering with toluene. The X-ray single crystal analysis shows that the compound consists of two isolated Sn9 clusters and two Sn9 clusters connected by a mercury atom.

AB - The title compound [K([2,2,2]crypt)]12[Sn9] 2[Sn9HgSn9] has been obtained by reaction of elemental mercury with the binary phase K4Sn9 in ethylenediamine after addition of [2,2,2]crypt and layering with toluene. The X-ray single crystal analysis shows that the compound consists of two isolated Sn9 clusters and two Sn9 clusters connected by a mercury atom.

KW - Cluster compounds

KW - Crystal structure

KW - Mercury

KW - Tin

KW - Zintl ions

UR - https://www.scopus.com/pages/publications/77954338180

U2 - 10.1002/zaac.201000103

DO - 10.1002/zaac.201000103

M3 - Article

AN - SCOPUS:77954338180

SN - 0044-2313

VL - 636

SP - 1293

EP - 1296

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 7

ER -

[Sn₉HgSn₉]^6-: An intermetalloid Zintl ion with two Sn₉ connected by heteroatom

Abstract

Keywords

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