[Sn17{GaCl(ddp)}4]: A high-nuclearity metalloid tin cluster trapped by electrophilic gallium ligands

Ganesan Prabusankar; Andreas Kempter; Christian Gemel; Marie Katrin Schöter; Roland A. Fischer

doi:10.1002/anie.200802470

[Sn₁₇{GaCl(ddp)}₄]: A high-nuclearity metalloid tin cluster trapped by electrophilic gallium ligands

Ganesan Prabusankar
, Andreas Kempter
, Christian Gemel
, Marie Katrin Schöter
, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

80 Scopus citations

Abstract

(Chemical Equation Presented) The reduction of SnCl₂ by the low-valent gallium(I) β-diketiminate Ga^I(ddp) gives the title complex, which is best described as a Zintl-type anionic [Sn₁₇] ^4- cluster stabilized by an electrophilic shell of gallium ligands. This reaction could represent a new concept for the synthesis of metalloid main-group clusters. ddp = HC(CMeNC₆H₃-2,6-iPr ₂)₂.

Original language	English
Pages (from-to)	7234-7237
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	47
Issue number	38
DOIs	https://doi.org/10.1002/anie.200802470
State	Published - 8 Sep 2008
Externally published	Yes

Keywords

Gallium
Group 13 ligands
Metalloid clusters
Tin

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10.1002/anie.200802470

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title = "[Sn17\{GaCl(ddp)\}4]: A high-nuclearity metalloid tin cluster trapped by electrophilic gallium ligands",

abstract = "(Chemical Equation Presented) The reduction of SnCl2 by the low-valent gallium(I) β-diketiminate GaI(ddp) gives the title complex, which is best described as a Zintl-type anionic [Sn17] 4- cluster stabilized by an electrophilic shell of gallium ligands. This reaction could represent a new concept for the synthesis of metalloid main-group clusters. ddp = HC(CMeNC6H3-2,6-iPr 2)2.",

keywords = "Gallium, Group 13 ligands, Metalloid clusters, Tin",

author = "Ganesan Prabusankar and Andreas Kempter and Christian Gemel and Sch{\"o}ter, \{Marie Katrin\} and Fischer, \{Roland A.\}",

year = "2008",

month = sep,

day = "8",

doi = "10.1002/anie.200802470",

language = "English",

volume = "47",

pages = "7234--7237",

journal = "Angewandte Chemie International Edition in English",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "38",

}

TY - JOUR

T1 - [Sn17{GaCl(ddp)}4]

T2 - A high-nuclearity metalloid tin cluster trapped by electrophilic gallium ligands

AU - Prabusankar, Ganesan

AU - Kempter, Andreas

AU - Gemel, Christian

AU - Schöter, Marie Katrin

AU - Fischer, Roland A.

PY - 2008/9/8

Y1 - 2008/9/8

N2 - (Chemical Equation Presented) The reduction of SnCl2 by the low-valent gallium(I) β-diketiminate GaI(ddp) gives the title complex, which is best described as a Zintl-type anionic [Sn17] 4- cluster stabilized by an electrophilic shell of gallium ligands. This reaction could represent a new concept for the synthesis of metalloid main-group clusters. ddp = HC(CMeNC6H3-2,6-iPr 2)2.

AB - (Chemical Equation Presented) The reduction of SnCl2 by the low-valent gallium(I) β-diketiminate GaI(ddp) gives the title complex, which is best described as a Zintl-type anionic [Sn17] 4- cluster stabilized by an electrophilic shell of gallium ligands. This reaction could represent a new concept for the synthesis of metalloid main-group clusters. ddp = HC(CMeNC6H3-2,6-iPr 2)2.

KW - Gallium

KW - Group 13 ligands

KW - Metalloid clusters

KW - Tin

UR - https://www.scopus.com/pages/publications/53249117702

U2 - 10.1002/anie.200802470

DO - 10.1002/anie.200802470

M3 - Article

AN - SCOPUS:53249117702

SN - 1433-7851

VL - 47

SP - 7234

EP - 7237

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 38

ER -

[Sn₁₇{GaCl(ddp)}₄]: A high-nuclearity metalloid tin cluster trapped by electrophilic gallium ligands

Abstract

Keywords

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