Simultaneous introduction of various palladium active sites into MOF: Via one-pot synthesis: Pd at[Cu3- xPdx(BTC)2]n

Wenhua Zhang; Zhihao Chen; Majd Al-Naji; Penghu Guo; Stefan Cwik; Olesia Halbherr; Yuemin Wang; Martin Muhler; Nicole Wilde; Roger Gläser; Roland A. Fischer

doi:10.1039/c6dt02893d

Simultaneous introduction of various palladium active sites into MOF: Via one-pot synthesis: Pd at[Cu_{3- x}Pd_x(BTC)₂]_n

Wenhua Zhang
, Zhihao Chen
, Majd Al-Naji
, Penghu Guo
, Stefan Cwik
, Olesia Halbherr
, Yuemin Wang
, Martin Muhler
, Nicole Wilde
, Roger Gläser
, Roland A. Fischer

Chair of Inorganic and Organometallic Chemistry

Max-Planck-lnstitut für Kohlenforschung
University of Leipzig
Humanoid Technologies Lab (H2T)

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Simultaneous incorporation of palladium within Pd-Pd and/or Pd-Cu paddlewheels as framework-nodes and Pd nanoparticle (NP) dispersion into MOF have been achieved for the first time via one-pot synthesis. In particular, the framework substitution of Cu²⁺ by Pd²⁺ as well as the pore loading with PdNPs have been confirmed and characterized by XPS. The obtained solids featuring such multiple Pd-sites show enhanced catalytic activity in the aqueous-phase hydrogenation of p-nitrophenol (PNP) with NaBH₄ to p-aminophenol (PAP).

Original language	English
Pages (from-to)	14883-14887
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	38
DOIs	https://doi.org/10.1039/c6dt02893d
State	Published - 2016

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title = "Simultaneous introduction of various palladium active sites into MOF: Via one-pot synthesis: Pd at[Cu3- xPdx(BTC)2]n",

abstract = "Simultaneous incorporation of palladium within Pd-Pd and/or Pd-Cu paddlewheels as framework-nodes and Pd nanoparticle (NP) dispersion into MOF have been achieved for the first time via one-pot synthesis. In particular, the framework substitution of Cu2+ by Pd2+ as well as the pore loading with PdNPs have been confirmed and characterized by XPS. The obtained solids featuring such multiple Pd-sites show enhanced catalytic activity in the aqueous-phase hydrogenation of p-nitrophenol (PNP) with NaBH4 to p-aminophenol (PAP).",

author = "Wenhua Zhang and Zhihao Chen and Majd Al-Naji and Penghu Guo and Stefan Cwik and Olesia Halbherr and Yuemin Wang and Martin Muhler and Nicole Wilde and Roger Gl{\"a}ser and Fischer, \{Roland A.\}",

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year = "2016",

doi = "10.1039/c6dt02893d",

language = "English",

volume = "45",

pages = "14883--14887",

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T1 - Simultaneous introduction of various palladium active sites into MOF

T2 - Via one-pot synthesis: Pd at[Cu3- xPdx(BTC)2]n

AU - Zhang, Wenhua

AU - Chen, Zhihao

AU - Al-Naji, Majd

AU - Guo, Penghu

AU - Cwik, Stefan

AU - Halbherr, Olesia

AU - Wang, Yuemin

AU - Muhler, Martin

AU - Wilde, Nicole

AU - Gläser, Roger

AU - Fischer, Roland A.

PY - 2016

Y1 - 2016

N2 - Simultaneous incorporation of palladium within Pd-Pd and/or Pd-Cu paddlewheels as framework-nodes and Pd nanoparticle (NP) dispersion into MOF have been achieved for the first time via one-pot synthesis. In particular, the framework substitution of Cu2+ by Pd2+ as well as the pore loading with PdNPs have been confirmed and characterized by XPS. The obtained solids featuring such multiple Pd-sites show enhanced catalytic activity in the aqueous-phase hydrogenation of p-nitrophenol (PNP) with NaBH4 to p-aminophenol (PAP).

AB - Simultaneous incorporation of palladium within Pd-Pd and/or Pd-Cu paddlewheels as framework-nodes and Pd nanoparticle (NP) dispersion into MOF have been achieved for the first time via one-pot synthesis. In particular, the framework substitution of Cu2+ by Pd2+ as well as the pore loading with PdNPs have been confirmed and characterized by XPS. The obtained solids featuring such multiple Pd-sites show enhanced catalytic activity in the aqueous-phase hydrogenation of p-nitrophenol (PNP) with NaBH4 to p-aminophenol (PAP).

UR - https://www.scopus.com/pages/publications/84989910552

U2 - 10.1039/c6dt02893d

DO - 10.1039/c6dt02893d

M3 - Article

AN - SCOPUS:84989910552

SN - 1477-9226

VL - 45

SP - 14883

EP - 14887

JO - Dalton Transactions

JF - Dalton Transactions

IS - 38

ER -

Simultaneous introduction of various palladium active sites into MOF: Via one-pot synthesis: Pd at[Cu_{3- x}Pd_x(BTC)₂]_n

Abstract

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