Silver clusters intercalation into the cellulose matrix. I. Characteristics and properties of intercalates by WAXS, EDXA, IR, 13C NMR, XPS and Raman spectroscopy methods

N. E. Kotelnikova; G. Wegener; T. Paakkari; R. Serimaa; E. Windeisen; H. Knozinger; M. Scheithauer; V. N. Demidov; A. V. Shchukarev; A. V. Gribanov

Silver clusters intercalation into the cellulose matrix. I. Characteristics and properties of intercalates by WAXS, EDXA, IR, ¹³C NMR, XPS and Raman spectroscopy methods

N. E. Kotelnikova, G. Wegener, T. Paakkari, R. Serimaa, E. Windeisen, H. Knozinger, M. Scheithauer, V. N. Demidov, A. V. Shchukarev, A. V. Gribanov

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Silver ions' diffusion into the microcrystalline cellulose matrix and its subsequent reduction by means of both reducing properties of the matrix itself and specific reducers gives cellulose materials containing silver with a degree of oxidation 0. The highest quantity of silver intercalation into the cellulose matrix is attained by using glycerol as solvent and potassium hypophosphite and sodium boron hydrate as reducers. Maximum content of metallic silver reduced in cellulose matrix is 7.6 mass. % in bulk and 16.5 mass. % on the fibre cellulose surface.

Original language	English
Pages (from-to)	445-458
Number of pages	14
Journal	Cellulose Chemistry and Technology
Volume	36
Issue number	5-6
State	Published - Sep 2002
Externally published	Yes

Keywords

C NMR
EDXA
IR
Microcrystalline cellulose
Raman spectroscopy
Reduction
Silver ions
Silver with 0 degree of oxidation
WAXS
XPS

Cite this

Kotelnikova, N. E., Wegener, G., Paakkari, T., Serimaa, R., Windeisen, E., Knozinger, H., Scheithauer, M., Demidov, V. N., Shchukarev, A. V., & Gribanov, A. V. (2002). Silver clusters intercalation into the cellulose matrix. I. Characteristics and properties of intercalates by WAXS, EDXA, IR, ¹³C NMR, XPS and Raman spectroscopy methods. Cellulose Chemistry and Technology, 36(5-6), 445-458.

@article{7df7f2475ea04a20b7a1929b33015efe,

title = "Silver clusters intercalation into the cellulose matrix. I. Characteristics and properties of intercalates by WAXS, EDXA, IR, 13C NMR, XPS and Raman spectroscopy methods",

abstract = "Silver ions' diffusion into the microcrystalline cellulose matrix and its subsequent reduction by means of both reducing properties of the matrix itself and specific reducers gives cellulose materials containing silver with a degree of oxidation 0. The highest quantity of silver intercalation into the cellulose matrix is attained by using glycerol as solvent and potassium hypophosphite and sodium boron hydrate as reducers. Maximum content of metallic silver reduced in cellulose matrix is 7.6 mass. % in bulk and 16.5 mass. % on the fibre cellulose surface.",

keywords = "C NMR, EDXA, IR, Microcrystalline cellulose, Raman spectroscopy, Reduction, Silver ions, Silver with 0 degree of oxidation, WAXS, XPS",

author = "Kotelnikova, {N. E.} and G. Wegener and T. Paakkari and R. Serimaa and E. Windeisen and H. Knozinger and M. Scheithauer and Demidov, {V. N.} and Shchukarev, {A. V.} and Gribanov, {A. V.}",

year = "2002",

month = sep,

language = "English",

volume = "36",

pages = "445--458",

journal = "Cellulose Chemistry and Technology",

issn = "0576-9787",

publisher = "Editura Academiei Romane",

number = "5-6",

}

Kotelnikova, NE, Wegener, G, Paakkari, T, Serimaa, R, Windeisen, E, Knozinger, H, Scheithauer, M, Demidov, VN, Shchukarev, AV & Gribanov, AV 2002, 'Silver clusters intercalation into the cellulose matrix. I. Characteristics and properties of intercalates by WAXS, EDXA, IR, ¹³C NMR, XPS and Raman spectroscopy methods', Cellulose Chemistry and Technology, vol. 36, no. 5-6, pp. 445-458.

Silver clusters intercalation into the cellulose matrix. I. Characteristics and properties of intercalates by WAXS, EDXA, IR, ¹³C NMR, XPS and Raman spectroscopy methods. / Kotelnikova, N. E.; Wegener, G.; Paakkari, T. et al.
In: Cellulose Chemistry and Technology, Vol. 36, No. 5-6, 09.2002, p. 445-458.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Silver clusters intercalation into the cellulose matrix. I. Characteristics and properties of intercalates by WAXS, EDXA, IR, 13C NMR, XPS and Raman spectroscopy methods

AU - Kotelnikova, N. E.

AU - Wegener, G.

AU - Paakkari, T.

AU - Serimaa, R.

AU - Windeisen, E.

AU - Knozinger, H.

AU - Scheithauer, M.

AU - Demidov, V. N.

AU - Shchukarev, A. V.

AU - Gribanov, A. V.

PY - 2002/9

Y1 - 2002/9

N2 - Silver ions' diffusion into the microcrystalline cellulose matrix and its subsequent reduction by means of both reducing properties of the matrix itself and specific reducers gives cellulose materials containing silver with a degree of oxidation 0. The highest quantity of silver intercalation into the cellulose matrix is attained by using glycerol as solvent and potassium hypophosphite and sodium boron hydrate as reducers. Maximum content of metallic silver reduced in cellulose matrix is 7.6 mass. % in bulk and 16.5 mass. % on the fibre cellulose surface.

AB - Silver ions' diffusion into the microcrystalline cellulose matrix and its subsequent reduction by means of both reducing properties of the matrix itself and specific reducers gives cellulose materials containing silver with a degree of oxidation 0. The highest quantity of silver intercalation into the cellulose matrix is attained by using glycerol as solvent and potassium hypophosphite and sodium boron hydrate as reducers. Maximum content of metallic silver reduced in cellulose matrix is 7.6 mass. % in bulk and 16.5 mass. % on the fibre cellulose surface.

KW - C NMR

KW - EDXA

KW - IR

KW - Microcrystalline cellulose

KW - Raman spectroscopy

KW - Reduction

KW - Silver ions

KW - Silver with 0 degree of oxidation

KW - WAXS

KW - XPS

UR - http://www.scopus.com/inward/record.url?scp=0037705706&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0037705706

SN - 0576-9787

VL - 36

SP - 445

EP - 458

JO - Cellulose Chemistry and Technology

JF - Cellulose Chemistry and Technology

IS - 5-6

ER -

Silver clusters intercalation into the cellulose matrix. I. Characteristics and properties of intercalates by WAXS, EDXA, IR, ¹³C NMR, XPS and Raman spectroscopy methods

Abstract

Keywords

Other files and links

Fingerprint

Cite this