Silicon and Germanium Compounds with Amidinate Ligands Hans

Hans H. Karsch, Thomas Segmuller

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

Abstract

A series of penta- and hexacoordinate silicon and germanium compounds with amidinate ligands have been synthesized and investigated spectroscopically and structurally. In contrast to silicon, germanium also forms stable compounds with amidinate ligands in the +2 valence state.

Original languageEnglish
Title of host publicationOrganosilicon Chemistry Set
Subtitle of host publicationFrom Molecules to Materials
Publisherwiley
Pages270-276
Number of pages7
ISBN (Electronic)9783527620777
ISBN (Print)9783527323470
DOIs
StatePublished - 10 Jun 2008

Keywords

  • Germanium amidinates
  • Hypervalency
  • Low valency
  • Silicon amidinates

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